{"title":"磁性纳米颗粒支撑的铜(II)络合物:作为制备二芳基(芳基-杂环)硒化物的活性磁性可回收催化剂的 Fe3O4@DABA-PQ-CuCl2 纳米复合材料","authors":"Wei Li , Wenjing Xu , Jinlong Yan , Li Yan Zhang","doi":"10.1080/17415993.2023.2255713","DOIUrl":null,"url":null,"abstract":"<div><p>During the last few years, research on new approaches for the synthesis of diaryl selenides containing heterocyclic compounds (Heterocyclic-Selenide-Aryl derivatives) has gained special importance among chemists. These compounds are very valuable from pharmaceutical and pharmacological points of view, and several biological properties such as anti-cancer and antitumor properties have been reported about them. In this research, we presented an ecofriendly and efficient method to prepare diaryl selenides containing heterocyclic compounds through one-pot three-component reactions of heterocyclic compounds with aryl iodides and selenium catalyzed by Fe<sub>3</sub>O<sub>4</sub>@DABA-PQ-CuCl<sub>2</sub> nanocomposite in PEG as solvent under thermal conditions. Fe<sub>3</sub>O<sub>4</sub>@DABA-PQ-CuCl<sub>2</sub> nanocomposite was successfully fabricated by using simple method and was fully identified by several spectroscopic techniques. The use of nanocatalysts synthesized in this work has the following advantages over the catalysts reported in the articles: low toxicity, easy storage, transportation, weighing and application, easy preparation of catalyst from cheap and available raw materials, high activity of catalyst due to increased surface area, stability in solvents and at high temperatures, high selectivity, recyclability and reuse of catalyst.</p></div>","PeriodicalId":17081,"journal":{"name":"Journal of Sulfur Chemistry","volume":"45 1","pages":"Pages 42-64"},"PeriodicalIF":2.1000,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Magnetic nanoparticles supported copper (II) complex: Fe3O4@DABA-PQ-CuCl2 nanocomposite as an active magnetically recoverable catalyst for preparation of diaryl (aryl-heterocyclic) selenides\",\"authors\":\"Wei Li , Wenjing Xu , Jinlong Yan , Li Yan Zhang\",\"doi\":\"10.1080/17415993.2023.2255713\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>During the last few years, research on new approaches for the synthesis of diaryl selenides containing heterocyclic compounds (Heterocyclic-Selenide-Aryl derivatives) has gained special importance among chemists. These compounds are very valuable from pharmaceutical and pharmacological points of view, and several biological properties such as anti-cancer and antitumor properties have been reported about them. In this research, we presented an ecofriendly and efficient method to prepare diaryl selenides containing heterocyclic compounds through one-pot three-component reactions of heterocyclic compounds with aryl iodides and selenium catalyzed by Fe<sub>3</sub>O<sub>4</sub>@DABA-PQ-CuCl<sub>2</sub> nanocomposite in PEG as solvent under thermal conditions. Fe<sub>3</sub>O<sub>4</sub>@DABA-PQ-CuCl<sub>2</sub> nanocomposite was successfully fabricated by using simple method and was fully identified by several spectroscopic techniques. The use of nanocatalysts synthesized in this work has the following advantages over the catalysts reported in the articles: low toxicity, easy storage, transportation, weighing and application, easy preparation of catalyst from cheap and available raw materials, high activity of catalyst due to increased surface area, stability in solvents and at high temperatures, high selectivity, recyclability and reuse of catalyst.</p></div>\",\"PeriodicalId\":17081,\"journal\":{\"name\":\"Journal of Sulfur Chemistry\",\"volume\":\"45 1\",\"pages\":\"Pages 42-64\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Sulfur Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1741599323000910\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Sulfur Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1741599323000910","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Magnetic nanoparticles supported copper (II) complex: Fe3O4@DABA-PQ-CuCl2 nanocomposite as an active magnetically recoverable catalyst for preparation of diaryl (aryl-heterocyclic) selenides
During the last few years, research on new approaches for the synthesis of diaryl selenides containing heterocyclic compounds (Heterocyclic-Selenide-Aryl derivatives) has gained special importance among chemists. These compounds are very valuable from pharmaceutical and pharmacological points of view, and several biological properties such as anti-cancer and antitumor properties have been reported about them. In this research, we presented an ecofriendly and efficient method to prepare diaryl selenides containing heterocyclic compounds through one-pot three-component reactions of heterocyclic compounds with aryl iodides and selenium catalyzed by Fe3O4@DABA-PQ-CuCl2 nanocomposite in PEG as solvent under thermal conditions. Fe3O4@DABA-PQ-CuCl2 nanocomposite was successfully fabricated by using simple method and was fully identified by several spectroscopic techniques. The use of nanocatalysts synthesized in this work has the following advantages over the catalysts reported in the articles: low toxicity, easy storage, transportation, weighing and application, easy preparation of catalyst from cheap and available raw materials, high activity of catalyst due to increased surface area, stability in solvents and at high temperatures, high selectivity, recyclability and reuse of catalyst.
期刊介绍:
The Journal of Sulfur Chemistry is an international journal for the dissemination of scientific results in the rapidly expanding realm of sulfur chemistry. The journal publishes high quality reviews, full papers and communications in the following areas: organic and inorganic chemistry, industrial chemistry, materials and polymer chemistry, biological chemistry and interdisciplinary studies directly related to sulfur science.
Papers outlining theoretical, physical, mechanistic or synthetic studies pertaining to sulfur chemistry are welcome. Hence the target audience is made up of academic and industrial chemists with peripheral or focused interests in sulfur chemistry. Manuscripts that truly define the aims of the journal include, but are not limited to, those that offer: a) innovative use of sulfur reagents; b) new synthetic approaches to sulfur-containing biomolecules, materials or organic and organometallic compounds; c) theoretical and physical studies that facilitate the understanding of sulfur structure, bonding or reactivity; d) catalytic, selective, synthetically useful or noteworthy transformations of sulfur containing molecules; e) industrial applications of sulfur chemistry; f) unique sulfur atom or molecule involvement in interfacial phenomena; g) descriptions of solid phase or combinatorial methods involving sulfur containing substrates. Submissions pertaining to related atoms such as selenium and tellurium are also welcome. Articles offering routine heterocycle formation through established reactions of sulfur containing substrates are outside the scope of the journal.