含环三磷腈的新型水溶性双桥萘二亚胺的合成、表征及其光物理和荧光传感器行为

IF 1.3 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Turkish Journal of Chemistry Pub Date : 2023-10-31 DOI:10.55730/1300-0527.3613

SÜREYYA OĞUZ TÜMAY, SERKAN YEŞİLOT

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引用次数: 0

摘要

制备了一种新型的双桥萘二亚胺附加环三磷腈水溶性模板，并对其光物理性能和传感器性能进行了评价。采用核磁共振(1h, 13C, 31P)和质谱对新型双桥萘二亚胺附加环三磷腈(6)进行了表征。利用紫外可见吸收光谱和荧光光谱研究了化合物6在不同溶剂体系和不同浓度下的光物理行为。为了验证所获得的水溶性模板在不同应用中的可用性，我们研究了化合物6在许多不同竞争物质(有机酸、糖类、硝基芳香族化合物、阴离子和金属阳离子)存在下的荧光传感器性能。结果表明，化合物6在竞争种中仅对硝基芳香族有选择性。

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Synthesis, characterization, and photophysical and fluorescence sensor behaviors of a new water-soluble double-bridged naphthalene diimide appended cyclotriphosphazene

A new water-soluble template of double-bridged naphthalene diimide appended cyclotriphosphazene was prepared, and its photophysical and sensor behaviors were evaluated. The characterization of novel double-bridged naphthalene diimide appended cyclotriphosphazene (6) was carried out by NMR (1 H, 13C, 31P) and mass spectroscopies. The photophysical behaviors of compound 6 were evaluated by UV-Vis absorption and fluorescence spectroscopies in various solvent systems and different concentrations. As an application for usability of the obtained water-soluble template in different applications, the fluorescence sensor property of compound 6 was investigated in the presence of many different competing species (organic acids, saccharides, nitroaromatic compounds, anions, and metal cations). The results obtained showed that compound 6 had selectivity against only the nitroaromatic species among the competing species tested.

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来源期刊

Turkish Journal of Chemistry 化学-工程：化工

CiteScore

2.40

自引率

7.10%

发文量

审稿时长

3 months

期刊介绍： The Turkish Journal of Chemistry is a bimonthly multidisciplinary journal published by the Scientific and Technological Research Council of Turkey (TÜBİTAK). The journal is dedicated to dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, polymeric, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences especially in chemical engineering where molecular aspects are key to the findings. The journal accepts English-language original manuscripts and contribution is open to researchers of all nationalities. The journal publishes refereed original papers, reviews, letters to editor and issues devoted to special fields. All manuscripts are peer-reviewed and electronic processing ensures accurate reproduction of text and data, plus publication times as short as possible.