高频电导氨分析仪的新型船载现场应用,用于描述水生生态系统的空间变化特征

IF 2.1 3区 地球科学 Q2 LIMNOLOGY
Emily T. Richardson, Angela M. Hansen, Tamara E. C. Kraus, Bryan D. Downing, Don Forsberg, John Stillian, Katy O'Donnell, Crystal L. Sturgeon, Brian A. Bergamaschi
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引用次数: 0

摘要

在适当的时间和空间尺度上记录溶解无机氮(DIN)的浓度和形态是了解水生生态系统健康的关键,特别是因为DIN为初级生产力提供燃料。除了点源和非点源的养分输入外,水文、地貌、温度、光照和生物地球化学转化等因素也会影响地表水的养分动态,从而形成陡峭的空间梯度和斑块。记录营养物的可变性对于确定来源、量化转化率和理解驱动因素也是必要的。由于后勤和成本的限制,通常不可能采用离散采样和实验室分析的方法来测量地表水中营养物质的浓度,其分辨率高到足以识别陡峭的空间梯度和斑块。由于这些限制,从离散采样产生的数据在空间和时间上是有限的,经常缺少关键变量。原位硝酸盐加亚硝酸盐(no3 -和no2 -)传感器技术的最新进展使no3 -具有高度的时间和空间分辨率水生生态系统中的浓度测量。然而,关于铵(nh4 +)浓度的可比信息仍然不可用。为了满足这一需求,美国地质调查局(US Geological Survey)与Timberline Instruments合作,对其商用台式TL-2800氨分析仪进行了改造,使其能够在流动模式下工作,在接收从移动的船上泵出的水的同时,能够以微摩尔(0.5 μM)的分辨率快速连续测量nh4 +浓度。虽然这种方法的实用性描述了空间调查,我们预计,它将适用于安装在固定站点连续监测nh4 +浓度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A novel boat-based field application of a high-frequency conductometric ammonium analyzer to characterize spatial variation in aquatic ecosystems

A novel boat-based field application of a high-frequency conductometric ammonium analyzer to characterize spatial variation in aquatic ecosystems

Documenting dissolved inorganic nitrogen (DIN) concentrations and forms at appropriate temporal and spatial scales is key to understanding aquatic ecosystem health, particularly because DIN fuels primary productivity. In addition to point and nonpoint source nutrient inputs, factors such as hydrology, geomorphology, temperature, light, and biogeochemical transformations influence nutrient dynamics in surface waters, allowing for the formation of steep spatial gradients and patchiness. Documenting nutrient variability is also necessary to identify sources, quantify transformation rates, and understand drivers. Because of logistical and cost constraints, it is often unfeasible to measure concentrations of nutrients in surface waters using discrete sampling followed by laboratory analysis at a resolution high enough to identify steep spatial gradients and patchiness. Because of these constraints, data generated from discrete sampling are limited in space and time, often missing key variabilities. Recent advancements of in situ nitrate plus nitrite ( NO 3 and NO 2 ) sensor technology have enabled highly temporally and spatially resolved NO 3 concentration measurements in aquatic ecosystems. However, comparable information about ammonium ( NH 4 + ) concentrations remains unavailable. To address this need, US Geological Survey collaborated with Timberline Instruments to modify their commercially available benchtop TL-2800 ammonia analyzer to operate in flow-through mode, enabling rapid continuous NH 4 + concentration measurements at a micromolar (0.5 μM) resolution while receiving water pumped from a moving boat. Although the utility of this method is described for spatial surveys, we anticipate that it would be adaptable to installation at a fixed station for continuous monitoring of NH 4 + concentration.

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来源期刊
CiteScore
4.80
自引率
3.70%
发文量
56
审稿时长
3 months
期刊介绍: Limnology and Oceanography: Methods (ISSN 1541-5856) is a companion to ASLO''s top-rated journal Limnology and Oceanography, and articles are held to the same high standards. In order to provide the most rapid publication consistent with high standards, Limnology and Oceanography: Methods appears in electronic format only, and the entire submission and review system is online. Articles are posted as soon as they are accepted and formatted for publication. Limnology and Oceanography: Methods will consider manuscripts whose primary focus is methodological, and that deal with problems in the aquatic sciences. Manuscripts may present new measurement equipment, techniques for analyzing observations or samples, methods for understanding and interpreting information, analyses of metadata to examine the effectiveness of approaches, invited and contributed reviews and syntheses, and techniques for communicating and teaching in the aquatic sciences.
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