Janus二聚体的自扩散电泳和对称破缺:解析解

IF 2.2 3区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES
Symmetry-Basel Pub Date : 2023-11-03 DOI:10.3390/sym15112019
Eldad J. Avital, Touvia Miloh
{"title":"Janus二聚体的自扩散电泳和对称破缺:解析解","authors":"Eldad J. Avital, Touvia Miloh","doi":"10.3390/sym15112019","DOIUrl":null,"url":null,"abstract":"A self-diffusiophoretic problem is considered for a chemically active dimer consisting of two equal touching spherical colloids that are exposed to different fixed-flux and fixed-rate surface reactions. A new analytic solution for the autophoretic mobility of such a catalytic Janus dimer is presented in the limit of a small Péclet number and linearization of the resulting Robin-type boundary value problem for the harmonic solute concentration. Explicit solutions in terms of the physical parameters are first obtained for the uncoupled electrostatic and hydrodynamic problems. The dimer mobility is then found by employing the reciprocal theorem depending on the surface slip velocity and on the normal component of the shear stress acting on the inert dimer. Special attention is given to the limiting case of a Janus dimer composed of an inert sphere and a chemically active sphere where the fixed-rate reaction (Damköhler number) is infinitely large. Examples are given, comparing the numerical and approximate analytic solutions of the newly developed theory. Singular points arising in the model are discussed for a dimer with a fixed-rate reaction, and the flow field around the dimer is also analysed. The new developed theory introduces a fast way to compute the mobility of a freely suspended dimer and the induced flow field around it, and thus can also serve as a sub grid scale model for a multi-scale flow simulation.","PeriodicalId":48874,"journal":{"name":"Symmetry-Basel","volume":null,"pages":null},"PeriodicalIF":2.2000,"publicationDate":"2023-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Self-Diffusiophoresis and Symmetry-Breaking of a Janus Dimer: Analytic Solution\",\"authors\":\"Eldad J. Avital, Touvia Miloh\",\"doi\":\"10.3390/sym15112019\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A self-diffusiophoretic problem is considered for a chemically active dimer consisting of two equal touching spherical colloids that are exposed to different fixed-flux and fixed-rate surface reactions. A new analytic solution for the autophoretic mobility of such a catalytic Janus dimer is presented in the limit of a small Péclet number and linearization of the resulting Robin-type boundary value problem for the harmonic solute concentration. Explicit solutions in terms of the physical parameters are first obtained for the uncoupled electrostatic and hydrodynamic problems. The dimer mobility is then found by employing the reciprocal theorem depending on the surface slip velocity and on the normal component of the shear stress acting on the inert dimer. Special attention is given to the limiting case of a Janus dimer composed of an inert sphere and a chemically active sphere where the fixed-rate reaction (Damköhler number) is infinitely large. Examples are given, comparing the numerical and approximate analytic solutions of the newly developed theory. Singular points arising in the model are discussed for a dimer with a fixed-rate reaction, and the flow field around the dimer is also analysed. The new developed theory introduces a fast way to compute the mobility of a freely suspended dimer and the induced flow field around it, and thus can also serve as a sub grid scale model for a multi-scale flow simulation.\",\"PeriodicalId\":48874,\"journal\":{\"name\":\"Symmetry-Basel\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2023-11-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Symmetry-Basel\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/sym15112019\",\"RegionNum\":3,\"RegionCategory\":\"综合性期刊\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MULTIDISCIPLINARY SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Symmetry-Basel","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/sym15112019","RegionNum":3,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
引用次数: 0

摘要

考虑了一种化学活性二聚体的自扩散电泳问题,该二聚体由两个相等接触的球形胶体组成,暴露于不同的固定通量和固定速率表面反应。本文提出了一种新的解析解,用于分析这种催化Janus二聚体的自愈迁移率,该解在psamclet数很小的情况下,并对所得的robin型调和溶质浓度边值问题进行了线性化处理。首先对不耦合的静电和水动力问题得到了物理参数的显式解。二聚体的迁移率,然后通过采用依赖于表面滑移速度和作用在惰性二聚体上的剪切应力的法向分量的互易定理被发现。特别注意由惰性球和化学活性球组成的Janus二聚体的极限情况,其中固定速率反应(Damköhler数)无限大。给出了实例,比较了新理论的数值解和近似解析解。讨论了具有固定速率反应的二聚体在模型中出现的奇异点,并分析了二聚体周围的流场。新发展的理论引入了一种快速计算自由悬浮二聚体的迁移率及其周围诱导流场的方法,因此也可以作为多尺度流动模拟的亚网格尺度模型。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Self-Diffusiophoresis and Symmetry-Breaking of a Janus Dimer: Analytic Solution
A self-diffusiophoretic problem is considered for a chemically active dimer consisting of two equal touching spherical colloids that are exposed to different fixed-flux and fixed-rate surface reactions. A new analytic solution for the autophoretic mobility of such a catalytic Janus dimer is presented in the limit of a small Péclet number and linearization of the resulting Robin-type boundary value problem for the harmonic solute concentration. Explicit solutions in terms of the physical parameters are first obtained for the uncoupled electrostatic and hydrodynamic problems. The dimer mobility is then found by employing the reciprocal theorem depending on the surface slip velocity and on the normal component of the shear stress acting on the inert dimer. Special attention is given to the limiting case of a Janus dimer composed of an inert sphere and a chemically active sphere where the fixed-rate reaction (Damköhler number) is infinitely large. Examples are given, comparing the numerical and approximate analytic solutions of the newly developed theory. Singular points arising in the model are discussed for a dimer with a fixed-rate reaction, and the flow field around the dimer is also analysed. The new developed theory introduces a fast way to compute the mobility of a freely suspended dimer and the induced flow field around it, and thus can also serve as a sub grid scale model for a multi-scale flow simulation.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Symmetry-Basel
Symmetry-Basel MULTIDISCIPLINARY SCIENCES-
CiteScore
5.40
自引率
11.10%
发文量
2276
审稿时长
14.88 days
期刊介绍: Symmetry (ISSN 2073-8994), an international and interdisciplinary scientific journal, publishes reviews, regular research papers and short notes. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. There is no restriction on the length of the papers. Full experimental and/or methodical details must be provided, so that results can be reproduced.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信