Preparation of Pd/Ce(F)-MCM-48 catalysts and their catalytic performance of n-heptane isomerization

Abstract Ce and F were added to MCM-48 molecular sieve by hydrothermal synthesis, and Pd/Ce(F)-MCM-48 metal acid bifunctional catalysts were prepared by impregnation method. The physical and chemical properties of Ce(F)-MCM-48 and Pd/Ce(F)-MCM-48 were characterized by X-ray diffraction, scanning electron microscope, NH 3 temperature programmed desorption instrument, Fourier infrared spectrometer, and X-ray photoelectronic spectrometer characterization methods. The results showed that when the molar ratio of the raw materials was n (Ce): n (TEOS) = 0.02 and n (NaF): n (TEOS) = 0.10, Ce(F)-MCM-48-0.10 molecular sieve had a high degree of order and large specific surface area and pore volume, the total acid content increased, and the acid strength also increased. And it had an acidic center and generated certain oxygen vacancies. The catalyst prepared after Pd impregnation had good dispersibility. 0.4% Pd/Ce(F)-MCM-48-0.10 catalyst still maintained the crystalline phase of MCM-48 molecular sieve. A micro-reaction device was used to examine the catalytic performance of n -heptane isomerization of Pd/Ce(F)-MCM-48-0.10 catalysts. When the hydrogen flow rate was 30 mL·min −1 , reduction temperature was 300°C, reduction time was 4 h, weight hourly space velocity was 7.6 h −1 , and reaction temperature was 280°C, 0.4% Pd/Ce(F)-MCM-48-0.10 catalyst was used in the heptane isomerization reaction, where the conversion of n -heptane was 67.3% and the selectivity of isoheptane was 96.5%.