在自然日光照射下用于光催化应用的聚香兰素吡咯/氧化锌复合材料的合成与表征

IF 1 4区 化学 Q4 POLYMER SCIENCE
Anas Abderrahmane Lahouel, Mounir Mekidiche, Chahrazed Belmir, Abdelkader Slimane, Nabahat Sahli
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引用次数: 0

摘要

本研究通过实验研究了聚香兰素吡咯/氧化锌纳米复合材料在模拟太阳光照射下降解亚甲基蓝(MeB)染料的光催化活性。聚(香兰素吡咯)(PPHMB)及其衍生物等导电聚合物通常被用作光敏剂,以提高氧化锌在阳光照射下的光催化活性。在使用阳离子缩聚法生成 PPHMB 后,采用共沉淀法生成 PPHMB/ZnO 复合材料。在阳光照射下,生成的复合材料在破坏 MeB 染料方面比裸 ZnO 表现出更高的光催化活性。对制备的复合材料采用了多种表征方法,包括 XRD、TGA 和光学分析。还探讨了可能影响结果的不同操作因素,如起始染料浓度、使用的辐射量以及 PPHMB/ZnO 复合材料用量的影响。使用紫外可见分光光度计测定染料降解的光密度。此外,还研究了光催化活性的可重复性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis and Characterization of Poly(vanillin pyrrole)/Zinc Oxide Composite for Photocatalysis Application under Natural Sunlight Irradiation

Synthesis and Characterization of Poly(vanillin pyrrole)/Zinc Oxide Composite for Photocatalysis Application under Natural Sunlight Irradiation

In this investigation, methylene blue (MeB) dye degradation under simulated solar light irradiation was experimentally investigated for the photocatalytic activity of poly(vanillin pyrrole)/ZnO nanocomposite. Conducting polymers like poly(vanillin pyrrole) (PPHMB) and its derivatives are often employed as photosensitizers to enhance the photocatalytic activity of ZnO when exposed to sunlight. The co-precipitation approach was used to create the PPHMB/ZnO composite after the PPHMB was created using the cationic polycondensation method. Under sunlight irradiation, the produced composite demonstrated greater photocatalytic activity than bare ZnO for the destruction of MeB dye. A variety of characterization methods, including, XRD, TGA, and an optical analysis, were used to the produced composite. Different operational factors that might influence results, such as the starting dye concentration, the amount of radiation employed, and the impact of the dosage of PPHMB/ZnO composite, have also been explored. A UV-visible spectrophotometer was used to determine the optical density of dye degradation. Additionally, investigated was the photocatalytic activity’s repeatability.

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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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