{"title":"阿尔及利亚高岭土黏土(HKDD3)固定化硫化铁的合成及对亚甲基蓝的去除效果研究","authors":"Asma Hayoune, Hocine Akkari, Marcello Marelli, Valeria Pappalardo, Jia Yang, Muhammad Zubair","doi":"10.1002/sia.7268","DOIUrl":null,"url":null,"abstract":"The aim of this study is to functionalize an Algerian halloysite clay (kaolin Djebel Debbagh, HKDD3) with FeS nanoparticles by employing a hydrothermal approach and exploring its ability to remove methylene blue under visible light irradiation. The FeS‐HKDD3 photocatalyst was synthesized successfully and exhibited good crystallinity. Different techniques were used to characterize the produced photocatalyst, including XRD, STEM/EDS, TEM, BET, and UV–vis DRS in order to investigate its structure, morphology, and optical performance. The HKDD3 is a natural halloysite having a tubular shape with a length ranging from 500 nm to several micrometers and a diameter that is estimated from 50 to 100 nm. The iron sulfide nanoparticles are immobilized as cube aggregates on the surface of the halloysite. The visible range displayed a strong absorption of the obtained photocatalyst, with an estimated bandgap of 1.60 eV, according to UV–vis DRS findings. The results exhibited a higher efficiency toward synergic adsorption‐photocatalytic degradation effect for methylene blue dye removal.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.6000,"publicationDate":"2023-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and characterization of iron sulfide immobilized on Algerian halloysite clay (HKDD3) with enhanced removal of methylene blue from aqueous medium\",\"authors\":\"Asma Hayoune, Hocine Akkari, Marcello Marelli, Valeria Pappalardo, Jia Yang, Muhammad Zubair\",\"doi\":\"10.1002/sia.7268\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The aim of this study is to functionalize an Algerian halloysite clay (kaolin Djebel Debbagh, HKDD3) with FeS nanoparticles by employing a hydrothermal approach and exploring its ability to remove methylene blue under visible light irradiation. The FeS‐HKDD3 photocatalyst was synthesized successfully and exhibited good crystallinity. Different techniques were used to characterize the produced photocatalyst, including XRD, STEM/EDS, TEM, BET, and UV–vis DRS in order to investigate its structure, morphology, and optical performance. The HKDD3 is a natural halloysite having a tubular shape with a length ranging from 500 nm to several micrometers and a diameter that is estimated from 50 to 100 nm. The iron sulfide nanoparticles are immobilized as cube aggregates on the surface of the halloysite. The visible range displayed a strong absorption of the obtained photocatalyst, with an estimated bandgap of 1.60 eV, according to UV–vis DRS findings. The results exhibited a higher efficiency toward synergic adsorption‐photocatalytic degradation effect for methylene blue dye removal.\",\"PeriodicalId\":22062,\"journal\":{\"name\":\"Surface and Interface Analysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2023-11-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface and Interface Analysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/sia.7268\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface and Interface Analysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/sia.7268","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Synthesis and characterization of iron sulfide immobilized on Algerian halloysite clay (HKDD3) with enhanced removal of methylene blue from aqueous medium
The aim of this study is to functionalize an Algerian halloysite clay (kaolin Djebel Debbagh, HKDD3) with FeS nanoparticles by employing a hydrothermal approach and exploring its ability to remove methylene blue under visible light irradiation. The FeS‐HKDD3 photocatalyst was synthesized successfully and exhibited good crystallinity. Different techniques were used to characterize the produced photocatalyst, including XRD, STEM/EDS, TEM, BET, and UV–vis DRS in order to investigate its structure, morphology, and optical performance. The HKDD3 is a natural halloysite having a tubular shape with a length ranging from 500 nm to several micrometers and a diameter that is estimated from 50 to 100 nm. The iron sulfide nanoparticles are immobilized as cube aggregates on the surface of the halloysite. The visible range displayed a strong absorption of the obtained photocatalyst, with an estimated bandgap of 1.60 eV, according to UV–vis DRS findings. The results exhibited a higher efficiency toward synergic adsorption‐photocatalytic degradation effect for methylene blue dye removal.
期刊介绍:
Surface and Interface Analysis is devoted to the publication of papers dealing with the development and application of techniques for the characterization of surfaces, interfaces and thin films. Papers dealing with standardization and quantification are particularly welcome, and also those which deal with the application of these techniques to industrial problems. Papers dealing with the purely theoretical aspects of the technique will also be considered. Review articles will be published; prior consultation with one of the Editors is advised in these cases. Papers must clearly be of scientific value in the field and will be submitted to two independent referees. Contributions must be in English and must not have been published elsewhere, and authors must agree not to communicate the same material for publication to any other journal. Authors are invited to submit their papers for publication to John Watts (UK only), Jose Sanz (Rest of Europe), John T. Grant (all non-European countries, except Japan) or R. Shimizu (Japan only).