烯烃的氢磺化方法

IF 2.1 3区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Journal of Sulfur Chemistry Pub Date : 2024-05-03 DOI:10.1080/17415993.2023.2278602

Esmail Vessally , Media Noori Abdullah , Maha Dhurgham Azeez , Mohammad Reza Poor Heravi , Mohaned Adil , Mustafa Humam Sami , Ayat Hussein Adhab

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引用次数: 0

摘要

氢官能化是烯烃最重要的转化反应之一，通过在碳碳双键上安装官能团，可以快速增加分子的复杂性。在此背景下，过去几年中，通过烯烃双键的氢磺化反应合成具有重要生物意义的脂肪族砜的实验研究引起了极大关注，因为这种方法简单直接，原子和步骤经济性高，而且起始材料容易获得。本文旨在对这一研究课题的最新进展进行综述，并特别强调了反应的机理方面。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Methods for hydrosulfonylation of alkenes

Hydrofunctionalization is one of the most important transformation reactions of alkenes which allows for rapid increase in molecular complexity by installing functional groups across the carbon–carbon double bonds. In this context, over the past few years, the experimental synthesis of biologically important aliphatic sulfones through the hydrosulfonylation of olefinic double bonds has attracted tremendous attention due to its straightforward manner with high atom- and step-economy, and also easily accessible starting materials. The aim of the present paper is to perform a review of recent advances made on this research topic, with special emphasis on the mechanistic aspect of the reactions.

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来源期刊

Journal of Sulfur Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

4.10

自引率

9.10%

发文量

审稿时长

6-12 weeks

期刊介绍： The Journal of Sulfur Chemistry is an international journal for the dissemination of scientific results in the rapidly expanding realm of sulfur chemistry. The journal publishes high quality reviews, full papers and communications in the following areas: organic and inorganic chemistry, industrial chemistry, materials and polymer chemistry, biological chemistry and interdisciplinary studies directly related to sulfur science. Papers outlining theoretical, physical, mechanistic or synthetic studies pertaining to sulfur chemistry are welcome. Hence the target audience is made up of academic and industrial chemists with peripheral or focused interests in sulfur chemistry. Manuscripts that truly define the aims of the journal include, but are not limited to, those that offer: a) innovative use of sulfur reagents; b) new synthetic approaches to sulfur-containing biomolecules, materials or organic and organometallic compounds; c) theoretical and physical studies that facilitate the understanding of sulfur structure, bonding or reactivity; d) catalytic, selective, synthetically useful or noteworthy transformations of sulfur containing molecules; e) industrial applications of sulfur chemistry; f) unique sulfur atom or molecule involvement in interfacial phenomena; g) descriptions of solid phase or combinatorial methods involving sulfur containing substrates. Submissions pertaining to related atoms such as selenium and tellurium are also welcome. Articles offering routine heterocycle formation through established reactions of sulfur containing substrates are outside the scope of the journal.