镍(II)、铜(II)、锌(II)与十基黄药及其氮基配体加合物配合物的制备、表征及其生物活性

Q3 Chemistry
Mahameed AMEEN, Fadia AHMED
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引用次数: 0

摘要

本研究包括对Ni(II)、Cu(II)、Zn(II)等多个过渡金属离子的12种新的单核黄药配合物的合成和表征,并通过与配体(十基黄药钾)的相互作用,制备了式[M(DEXANT)2]的配合物:M= Ni(II)、Cu(II)、Zn(II),再与Lewis双齿碱相互作用,得到式[M(DEXANT)2]的配合物。L],其中L= 1,10-菲罗啉,8-羟基喹啉和2,2-联吡啶。采用熔点、原子吸收光谱、微量元素分析、红外光谱、质子核磁共振光谱、摩尔电导率、电子吸收光谱和磁化率等方法对所制备的配合物进行了表征。磁矩和电子能谱表明,[M(DEXANT)2]型配合物具有四面体几何形状,而[M(DEXANT)2]型配合物具有四面体几何形状。L]是八面体。电导率测量证明了所有化合物的非电解行为。对细菌种类的生物学评价表明,黄原酸配合物对所有类型的细菌都有效。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity
This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions Ni(II), Cu(II), and Zn(II) and through the interaction with ligand (potassium decyl xanthate) and complexes of formula [M(DEXANT)2] were prepared: M= Ni(II), Cu(II), and Zn(II), and then the interaction of these complexes with Lewis bidentate bases, to give complexes with the formula [M(DEXANT)2.L], where L= 1,10-phenanthroline, 8-hydroxyquinoline, and 2,2-bipyridine. The prepared complexes were characterized by melting point, atomic absorption spectrometry, micro elemental analysis, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, molar electrical conductivity, electronic absorption spectra, and magnetic susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type [M(DEXANT)2] had a tetrahedral geometry, while complexes of type [M(DEXANT)2.L] had an octahedral geometry. The conductivity measurements proved the non-electrolytic behavior of all compounds. The biological evaluation against bacterial species indicated that the xanthate complexes were effective against all bacterial types.
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来源期刊
CiteScore
1.60
自引率
0.00%
发文量
81
审稿时长
5 weeks
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