设计联动双光电开关实现光诱导固液相变和能量存储

IF 5.7 Q2 CHEMISTRY, PHYSICAL

ACS Materials Au Pub Date : 2023-09-26 DOI:10.1021/acsmaterialsau.3c00069

Alejandra Gonzalez, Qianfeng Qiu, Junichi Usuba, Joshua Wan and Grace G. D. Han*,

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引用次数: 0

摘要

我们展示了一种基于双偶氮苯支架的光开关相变材料的有效设计策略。这些化合物在 E,E 状态下显示出固相，在 Z,Z 状态下显示出液相，与之形成鲜明对比的是，它们的单偶氮苯同类化合物显示出的相变行为控制性较差，在很大程度上受到其官能团的影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Photoinduced Solid–Liquid Phase Transition and Energy Storage Enabled by the Design of Linked Double Photoswitches

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Photoinduced Solid–Liquid Phase Transition and Energy Storage Enabled by the Design of Linked Double Photoswitches

We demonstrate an effective design strategy of photoswitchable phase change materials based on the bis-azobenzene scaffold. These compounds display a solid phase in the E,E state and a liquid phase in the Z,Z state, in contrast to their monoazobenzene counterparts that exhibit less controlled phase transition behaviors that are largely influenced by their functional groups.

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来源期刊

ACS Materials Au 材料科学-

CiteScore

5.00

自引率

0.00%

发文量

期刊介绍： ACS Materials Au is an open access journal publishing letters articles reviews and perspectives describing high-quality research at the forefront of fundamental and applied research and at the interface between materials and other disciplines such as chemistry engineering and biology. Papers that showcase multidisciplinary and innovative materials research addressing global challenges are especially welcome. Areas of interest include but are not limited to:Design synthesis characterization and evaluation of forefront and emerging materialsUnderstanding structure property performance relationships and their underlying mechanismsDevelopment of materials for energy environmental biomedical electronic and catalytic applications