天然斜沸石分子筛骨架组成对Na+和Ca2+交换的影响

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Theoretical and Experimental Chemistry Pub Date : 2023-10-31 DOI:10.1007/s11237-023-09782-5

D. A. Krysenko, V. Ya. Demchenko

{"title":"天然斜沸石分子筛骨架组成对Na+和Ca2+交换的影响","authors":"D. A. Krysenko, V. Ya. Demchenko","doi":"10.1007/s11237-023-09782-5","DOIUrl":null,"url":null,"abstract":"<div><div><p>The effect of the zeolite framework composition on the selectivity and thermodynamic parameters of ion exchange is studied for the exchange reaction of Ca<sup>2+</sup> cations on Na-forms of clinoptilolites from nine deposits of Central and Southeast Europe, Northeast Asia, and North America. An increase in the thermodynamic affinity of Na-forms towards Ca<sup>2+</sup> cations is shown with a decrease in the Si/Al ratio in their zeolite framework.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"59 3","pages":"222 - 230"},"PeriodicalIF":0.7000,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of the Composition of the Zeolite Framework of Natural Clinoptilolites on the Exchange of Cations Na+ On Ca2+\",\"authors\":\"D. A. Krysenko, V. Ya. Demchenko\",\"doi\":\"10.1007/s11237-023-09782-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>The effect of the zeolite framework composition on the selectivity and thermodynamic parameters of ion exchange is studied for the exchange reaction of Ca<sup>2+</sup> cations on Na-forms of clinoptilolites from nine deposits of Central and Southeast Europe, Northeast Asia, and North America. An increase in the thermodynamic affinity of Na-forms towards Ca<sup>2+</sup> cations is shown with a decrease in the Si/Al ratio in their zeolite framework.</p></div></div>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":\"59 3\",\"pages\":\"222 - 230\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-10-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-023-09782-5\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-023-09782-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

研究了沸石骨架组成对钙离子交换选择性和离子交换热力学参数的影响。本文研究了来自中欧和东南欧、东北亚和北美9个沉积物的钙离子交换反应。随着分子筛结构中Si/Al比的降低，na -形式对Ca2+阳离子的热力学亲和力增加。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Effect of the Composition of the Zeolite Framework of Natural Clinoptilolites on the Exchange of Cations Na+ On Ca2+

查看原文本刊更多论文

Effect of the Composition of the Zeolite Framework of Natural Clinoptilolites on the Exchange of Cations Na+ On Ca2+

The effect of the zeolite framework composition on the selectivity and thermodynamic parameters of ion exchange is studied for the exchange reaction of Ca²⁺ cations on Na-forms of clinoptilolites from nine deposits of Central and Southeast Europe, Northeast Asia, and North America. An increase in the thermodynamic affinity of Na-forms towards Ca²⁺ cations is shown with a decrease in the Si/Al ratio in their zeolite framework.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.60

自引率

10.00%

发文量

审稿时长

6-12 weeks

期刊介绍： Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.