FeCoNiCrMo高熵合金纳米片催化氢化镁固态储氢

IF 5.6 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Tao Zhong, Haoyu Zhang, Mengchen Song, Yiqun Jiang, Danhong Shang, Fuying Wu, Liuting Zhang
{"title":"FeCoNiCrMo高熵合金纳米片催化氢化镁固态储氢","authors":"Tao Zhong,&nbsp;Haoyu Zhang,&nbsp;Mengchen Song,&nbsp;Yiqun Jiang,&nbsp;Danhong Shang,&nbsp;Fuying Wu,&nbsp;Liuting Zhang","doi":"10.1007/s12613-023-2669-7","DOIUrl":null,"url":null,"abstract":"<div><p>The catalytic effect of FeCoNiCrMo high entropy alloy nanosheets on the hydrogen storage performance of magnesium hydride (MgH<sub>2</sub>) was investigated for the first time in this paper. Experimental results demonstrated that 9wt% FeCoNiCrMo doped MgH<sub>2</sub> started to de-hydrogenate at 200°C and discharged up to 5.89wt% hydrogen within 60 min at 325°C. The fully dehydrogenated composite could absorb 3.23wt% hydrogen in 50 min at a temperature as low as 100°C. The calculated de/hydrogenation activation energy values decreased by 44.21%/55.22% compared with MgH<sub>2</sub>, respectively. Moreover, the composite’s hydrogen capacity dropped only 0.28wt% after 20 cycles, demonstrating remarkable cycling stability. The microstructure analysis verified that the five elements, Fe, Co, Ni, Cr, and Mo, remained stable in the form of high entropy alloy during the cycling process, and synergistically serving as a catalytic union to boost the de/hydrogenation reactions of MgH<sub>2</sub>. Besides, the FeCoNiCrMo nanosheets had close contact with MgH<sub>2</sub>, providing numerous non-homogeneous activation sites and diffusion channels for the rapid transfer of hydrogen, thus obtaining a superior catalytic effect.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 11","pages":"2270 - 2279"},"PeriodicalIF":5.6000,"publicationDate":"2023-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12613-023-2669-7.pdf","citationCount":"0","resultStr":"{\"title\":\"FeCoNiCrMo high entropy alloy nanosheets catalyzed magnesium hydride for solid-state hydrogen storage\",\"authors\":\"Tao Zhong,&nbsp;Haoyu Zhang,&nbsp;Mengchen Song,&nbsp;Yiqun Jiang,&nbsp;Danhong Shang,&nbsp;Fuying Wu,&nbsp;Liuting Zhang\",\"doi\":\"10.1007/s12613-023-2669-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The catalytic effect of FeCoNiCrMo high entropy alloy nanosheets on the hydrogen storage performance of magnesium hydride (MgH<sub>2</sub>) was investigated for the first time in this paper. Experimental results demonstrated that 9wt% FeCoNiCrMo doped MgH<sub>2</sub> started to de-hydrogenate at 200°C and discharged up to 5.89wt% hydrogen within 60 min at 325°C. The fully dehydrogenated composite could absorb 3.23wt% hydrogen in 50 min at a temperature as low as 100°C. The calculated de/hydrogenation activation energy values decreased by 44.21%/55.22% compared with MgH<sub>2</sub>, respectively. Moreover, the composite’s hydrogen capacity dropped only 0.28wt% after 20 cycles, demonstrating remarkable cycling stability. The microstructure analysis verified that the five elements, Fe, Co, Ni, Cr, and Mo, remained stable in the form of high entropy alloy during the cycling process, and synergistically serving as a catalytic union to boost the de/hydrogenation reactions of MgH<sub>2</sub>. Besides, the FeCoNiCrMo nanosheets had close contact with MgH<sub>2</sub>, providing numerous non-homogeneous activation sites and diffusion channels for the rapid transfer of hydrogen, thus obtaining a superior catalytic effect.</p></div>\",\"PeriodicalId\":14030,\"journal\":{\"name\":\"International Journal of Minerals, Metallurgy, and Materials\",\"volume\":\"30 11\",\"pages\":\"2270 - 2279\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2023-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s12613-023-2669-7.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Minerals, Metallurgy, and Materials\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12613-023-2669-7\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Minerals, Metallurgy, and Materials","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s12613-023-2669-7","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

本文首次研究了FeCoNiCrMo高熵合金纳米片对氢化镁(MgH2)储氢性能的催化作用。实验结果表明,9wt% FeCoNiCrMo掺杂的MgH2在200℃下开始脱氢,在325℃下60 min内放出高达5.89wt%的氢。在低至100℃的温度下,完全脱氢的复合材料可以在50 min内吸收3.23wt%的氢气。计算得到的脱氢化活化能值与MgH2相比分别降低了44.21%和55.22%。此外,经过20次循环后,复合材料的氢容量仅下降0.28wt%,表现出显著的循环稳定性。微观结构分析证实,Fe、Co、Ni、Cr和Mo五种元素在循环过程中以高熵合金的形式保持稳定,并协同促进MgH2的脱氢化反应。此外,FeCoNiCrMo纳米片与MgH2紧密接触,为氢的快速转移提供了大量非均质活化位点和扩散通道,从而获得了优异的催化效果。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
FeCoNiCrMo high entropy alloy nanosheets catalyzed magnesium hydride for solid-state hydrogen storage

The catalytic effect of FeCoNiCrMo high entropy alloy nanosheets on the hydrogen storage performance of magnesium hydride (MgH2) was investigated for the first time in this paper. Experimental results demonstrated that 9wt% FeCoNiCrMo doped MgH2 started to de-hydrogenate at 200°C and discharged up to 5.89wt% hydrogen within 60 min at 325°C. The fully dehydrogenated composite could absorb 3.23wt% hydrogen in 50 min at a temperature as low as 100°C. The calculated de/hydrogenation activation energy values decreased by 44.21%/55.22% compared with MgH2, respectively. Moreover, the composite’s hydrogen capacity dropped only 0.28wt% after 20 cycles, demonstrating remarkable cycling stability. The microstructure analysis verified that the five elements, Fe, Co, Ni, Cr, and Mo, remained stable in the form of high entropy alloy during the cycling process, and synergistically serving as a catalytic union to boost the de/hydrogenation reactions of MgH2. Besides, the FeCoNiCrMo nanosheets had close contact with MgH2, providing numerous non-homogeneous activation sites and diffusion channels for the rapid transfer of hydrogen, thus obtaining a superior catalytic effect.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
9.30
自引率
16.70%
发文量
205
审稿时长
2 months
期刊介绍: International Journal of Minerals, Metallurgy and Materials (Formerly known as Journal of University of Science and Technology Beijing, Mineral, Metallurgy, Material) provides an international medium for the publication of theoretical and experimental studies related to the fields of Minerals, Metallurgy and Materials. Papers dealing with minerals processing, mining, mine safety, environmental pollution and protection of mines, process metallurgy, metallurgical physical chemistry, structure and physical properties of materials, corrosion and resistance of materials, are viewed as suitable for publication.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信