研究氯菊酯等拟除虫菊酯农药在农业土壤中的吸附、保留和扩散及其作为过滤器的能力

Andrés Godínez-García, Pedro Jesús Díaz-Tecanhuey, Santiago Guijosa-Guadarrama, María Guadalupe Hernández-Morales
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引用次数: 0

摘要

这项工作是可持续发展优先事项之一的一部分,即保护土壤和保护含水层。众所周知,土壤是地下水中污染物的天然过滤器,因此最重要的目标之一是了解土壤和杀虫剂之间的相互作用,特别是拟除虫菊酯,这是当今最广泛使用的杀虫剂之一。以及这些物质在土壤中保持和扩散的过程。对拟除虫菊酯类农药在农业土壤样品中的迁移、扩散和滞留进行了系统研究。利用衰减全反射(ATR)傅里叶变换(FTIR)红外光谱技术定性测定了土壤中官能团的数量。以氯菊酯为拟除虫菊酯模型分子,利用氯菊酯悬浮液在水中的吸光度,监测了氯菊酯在土壤中吸附的定性浓度。显示了两种湿土的农药滞留能力,并测定了土床的质量流量。质量流的大小与土壤中官能团的数量成反比。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Estudio de adsorción, retención y difusión de pesticidas piretroides como la permetrina en suelo agrícola y su capacidad para actuar como filtro
This work is part of one of the priorities of sustainable development that is the conservation of soil and the care of aquifers. It is known that soil acts as a natural filter for contaminants in groundwater, so one of the most important objectives is to understand the interaction between soil and pesticides, especially pyrethroids, which are some of the most widely used today. as well as the process of retention and diffusion of these substances through the soil. A systematic study was carried out to determine the transfer, diffusion and retention of pyrethroid pesticides through agricultural soil samples. The kind of soils to be used in this study were identified, the quantity of functional groups was determined qualitatively using Infrared Spectroscopy by the Fourier Transform (FTIR) with Attenuated Total Reflection (ATR). Permethrin was taken as the pyrethroid model molecule, the qualitative concentration of permethrin absorbed in a soil bed was monitored using the absorbance of a suspension of permethrin in water. The pesticide retention capacity of two types of wet soil is shown and the mass flow through the soil bed was determined too. The magnitude of the mass flow was inversely related to the amount of functional groups in the soil.
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