{"title":"用于电线电缆应用的更快固化乙烯-硅烷共聚物","authors":"B. I. Chaudhary, Kurt Bolz, Peter Dreux","doi":"10.1109/td43745.2022.9816858","DOIUrl":null,"url":null,"abstract":"A “faster curing” ethylene-silane copolymer has been designed as an alternative to existing ethylene-silane copolymers or silane grafted polyethylenes. Rapid crosslinking at ambient conditions has been demonstrated with the “faster curing” co-polymer. Even with its enhanced cure characteristics, the “faster curing” co-polymer still exhibits excellent processability during melt extrusion. For applications where blends with non-silane functionalized polymers are desirable (or required), dilution with up to 50% LLDPE has been demonstrated while maintaining acceptable cure rate and extent of crosslinking, and even greater dilution is possible. The “faster curing” copolymer also maintains superior shelf-life stability over Sioplas silane grafted polyethylene. The “faster curing” copolymer is also a suitable alternative to Monosil silane grafted polyethylene and can be provided for use in bulk in addition to traditional boxes and bags.","PeriodicalId":241987,"journal":{"name":"2022 IEEE/PES Transmission and Distribution Conference and Exposition (T&D)","volume":"20 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2022-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Faster Curing Ethylene-Silane Copolymer for Wire and Cable Applications\",\"authors\":\"B. I. Chaudhary, Kurt Bolz, Peter Dreux\",\"doi\":\"10.1109/td43745.2022.9816858\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A “faster curing” ethylene-silane copolymer has been designed as an alternative to existing ethylene-silane copolymers or silane grafted polyethylenes. Rapid crosslinking at ambient conditions has been demonstrated with the “faster curing” co-polymer. Even with its enhanced cure characteristics, the “faster curing” co-polymer still exhibits excellent processability during melt extrusion. For applications where blends with non-silane functionalized polymers are desirable (or required), dilution with up to 50% LLDPE has been demonstrated while maintaining acceptable cure rate and extent of crosslinking, and even greater dilution is possible. The “faster curing” copolymer also maintains superior shelf-life stability over Sioplas silane grafted polyethylene. The “faster curing” copolymer is also a suitable alternative to Monosil silane grafted polyethylene and can be provided for use in bulk in addition to traditional boxes and bags.\",\"PeriodicalId\":241987,\"journal\":{\"name\":\"2022 IEEE/PES Transmission and Distribution Conference and Exposition (T&D)\",\"volume\":\"20 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-04-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2022 IEEE/PES Transmission and Distribution Conference and Exposition (T&D)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/td43745.2022.9816858\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2022 IEEE/PES Transmission and Distribution Conference and Exposition (T&D)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/td43745.2022.9816858","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Faster Curing Ethylene-Silane Copolymer for Wire and Cable Applications
A “faster curing” ethylene-silane copolymer has been designed as an alternative to existing ethylene-silane copolymers or silane grafted polyethylenes. Rapid crosslinking at ambient conditions has been demonstrated with the “faster curing” co-polymer. Even with its enhanced cure characteristics, the “faster curing” co-polymer still exhibits excellent processability during melt extrusion. For applications where blends with non-silane functionalized polymers are desirable (or required), dilution with up to 50% LLDPE has been demonstrated while maintaining acceptable cure rate and extent of crosslinking, and even greater dilution is possible. The “faster curing” copolymer also maintains superior shelf-life stability over Sioplas silane grafted polyethylene. The “faster curing” copolymer is also a suitable alternative to Monosil silane grafted polyethylene and can be provided for use in bulk in addition to traditional boxes and bags.