{"title":"为什么某些液体具有液晶性质","authors":"P. Adamski","doi":"10.1117/12.581138","DOIUrl":null,"url":null,"abstract":"The creation reasons of liquid crystal state have not explained up to now. This article is devoted for the elaboration a new solution of this problem. Author found the new calculation method of expression Σ(ri)2 which is a function of temperature, molecular weight and light wavelength. The Σ(ri)2 characterize the molecule of liquid and is connected with the distance polarizability tensor components αparallel1, αperpendicular1 by the formula. Σ(ri)2 = (Z ro)½ [(αparallel1)½/2 + (αperpendicular1)½]. For liquid crystal one can obtain two values of Σ(ri)2. First the Σ(ri)2To for the transition temperature To the isotropic liquid state of liquid crystal and second Σ(ri)2Tc for the transition temperature to the solid state of liquid Crystal. These quantities must to satisfy the relation Σ(ri)2To < Σ(ri)2Tc for all liquid crystals. If it is inversely the liquid does not possess the liquid crystal properties.","PeriodicalId":132866,"journal":{"name":"Liquid crystals (Print)","volume":"35 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2004-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Why certain liquids have the liquid crystal properties\",\"authors\":\"P. Adamski\",\"doi\":\"10.1117/12.581138\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The creation reasons of liquid crystal state have not explained up to now. This article is devoted for the elaboration a new solution of this problem. Author found the new calculation method of expression Σ(ri)2 which is a function of temperature, molecular weight and light wavelength. The Σ(ri)2 characterize the molecule of liquid and is connected with the distance polarizability tensor components αparallel1, αperpendicular1 by the formula. Σ(ri)2 = (Z ro)½ [(αparallel1)½/2 + (αperpendicular1)½]. For liquid crystal one can obtain two values of Σ(ri)2. First the Σ(ri)2To for the transition temperature To the isotropic liquid state of liquid crystal and second Σ(ri)2Tc for the transition temperature to the solid state of liquid Crystal. These quantities must to satisfy the relation Σ(ri)2To < Σ(ri)2Tc for all liquid crystals. If it is inversely the liquid does not possess the liquid crystal properties.\",\"PeriodicalId\":132866,\"journal\":{\"name\":\"Liquid crystals (Print)\",\"volume\":\"35 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Liquid crystals (Print)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1117/12.581138\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Liquid crystals (Print)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1117/12.581138","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
液晶态产生的原因至今没有得到解释。本文致力于阐述解决这一问题的新方法。建立了温度、分子量和波长的函数Σ(ri)2的新计算方法。Σ(ri)2表征了液体分子,并与距离极化张量分量α平行1、α垂直1通过公式联系起来。Σ(ri) 2 = (Z ro)½((αparallel1)½/ 2 +(αperpendicular1)½]。对于液晶,可以得到Σ(ri)2的两个值。首先是Σ(ri)2To为液晶向各向同性液态的转变温度,其次是Σ(ri)2Tc为液晶向固态的转变温度。对于所有液晶,这些量必须满足Σ(ri)2To < Σ(ri)2Tc的关系。如果相反,则液体不具有液晶性质。
Why certain liquids have the liquid crystal properties
The creation reasons of liquid crystal state have not explained up to now. This article is devoted for the elaboration a new solution of this problem. Author found the new calculation method of expression Σ(ri)2 which is a function of temperature, molecular weight and light wavelength. The Σ(ri)2 characterize the molecule of liquid and is connected with the distance polarizability tensor components αparallel1, αperpendicular1 by the formula. Σ(ri)2 = (Z ro)½ [(αparallel1)½/2 + (αperpendicular1)½]. For liquid crystal one can obtain two values of Σ(ri)2. First the Σ(ri)2To for the transition temperature To the isotropic liquid state of liquid crystal and second Σ(ri)2Tc for the transition temperature to the solid state of liquid Crystal. These quantities must to satisfy the relation Σ(ri)2To < Σ(ri)2Tc for all liquid crystals. If it is inversely the liquid does not possess the liquid crystal properties.