基于壳聚糖的碳钢绿色可持续缓蚀剂

C. Verma, Arumugam Madhan Kumar, M. Mazumder, M. Quraishi
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引用次数: 6

摘要

随着全球对“绿色化学”的需求日益增长,开发无毒环保的缓蚀剂是非常必要的。鉴于这几种形式的绿色缓蚀剂,如药物或药物、植物提取物、离子液体和由多组分反应(mcr)和机械化学混合产生的合成缓蚀剂正在被采用。目前,微波和超声辐照相结合的mcr是最好的绿色策略之一。天然多糖特别是壳聚糖衍生物取得了长足的进步。壳聚糖及其衍生物在各种腐蚀性介质中作为金属和合金的有效缓蚀剂。本章收集了已发表的关于壳聚糖及其衍生物抑制作用的主要研究成果。壳聚糖及其衍生物含有氨基(-NH2)、羟基(-OH)和乙酰基(-COCH3)等极性官能团,它们能有效地与金属表面结合,并起到吸附中心的作用,是利用壳聚糖及其衍生物作为有效缓蚀剂的基础。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Chitosan-Based Green and Sustainable Corrosion Inhibitors for Carbon Steel
Development of non-toxic and environmental friendly corrosion inhibitors is highly desirable owing to the increasing demands of “green chemistry” throughout the world. In view of these several forms of green corrosion inhibitors such as drugs or medicines, plant extracts, ionic liquids and synthetic inhibitors derived from multicomponent reactions (MCRs) and mechanochemical mixing are being employed. Nowadays, MCRs in association with microwave and ultrasound irradiations represent one of the best green strategies. Natural polysaccharides particularly chitosan derivatives gained substantial advancement. Chitosan and its several derivatives have been employed effective as corrosion inhibitors for metals and alloys in various aggressive media. The present chapter features the collection of major works that have been published on the inhibition effect of chitosan and its derivatives. The utilization of the chitosan and its derivatives as effective corrosion inhibitors is based on the fact that they contain several polar functional groups such as amino (-NH2), hydroxyl (-OH) and acetyl (-COCH3) groups that effectively bind with metallic surface and behave as adsorption centers.
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