可生物降解聚合物:机遇与挑战

M. Rosseto, C. Rigueto, D. Krein, N. P. Balbé, L. A. Massuda, A. Dettmer
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引用次数: 91

摘要

化石聚合物材料的过度使用产生了大量的废物,由于降解时间的原因,对环境造成了影响。技术的进步促使人们寻找有助于可持续发展的替代方案。在这种情况下,使用来自可再生资源的原料的可生物降解聚合物脱颖而出,因为它们具有形成薄膜的能力,并且来源丰富。此外,为了优化这一过程中的环境效益,可以对农业工业残留物进行评估,将其作为合成聚合物的原料,这些聚合物的物理、化学和机械性能是评估可能应用的重要因素。本章的建议是介绍目前对可再生资源的研究,包括农业和工业残留物,以获得可生物降解的聚合物,突出其性质和应用的可能性。评价硅橡胶液对壳聚糖和海藻酸盐膜配方的影响,以提高敷料的整体力学性能。研究发现,含有硅橡胶的膜具有更均匀的外观和足够的柔韧性和粘附性,抗拉强度增加,无论是否含有抗菌剂。此外,没有抗菌剂的膜导致所有生理溶液的吸收减少。研制壳聚糖/明胶复合膜,包埋不同数量的羊毛纳米颗粒。综上所述,在壳聚糖/明胶复合材料中掺入羊毛纳米颗粒可以降低膜的溶胀率、含水率、溶解度和降解率。然而,负载羊毛纳米颗粒后,薄膜的拉伸强度和断裂伸长率下降。研究了生物可降解的合成聚合物聚己二酸丁二酯(PBAT)薄膜,结论是饱和脂肪酸在12个碳原子之前的掺入降低了对水蒸气的渗透性,提高了淀粉、甘油和PBAT通过挤压生产的薄膜的机械性能,有助于形成具有凝聚力和均匀性的聚合物基质。增塑剂山梨醇麦芽糖醇增塑剂多元醇
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Biodegradable Polymers: Opportunities and Challenges
The overuse of polymer materials from fossil sources has generated a large volume of waste that causes environmental impacts due to the degradation time. The technological advance has stimulated the search for alternatives that can contribute to sustainability. In this context, the use of biodegradable polymers, that use raw materials from renewable sources stand out because they have that ability to form films and come from abundant sources. Also, in the expectation of optimizing the environmental benefits in this process, it is possible to value the agroindustrial residues, using them as raw material in the synthesis of the polymer, the physical, chemical and mechanical properties of these polymers are important to evaluate the possible applications. The proposal of this chapter is to present current research on renewable sources, including agricultural and industrial residues, to obtain biodegradable polymers, highlighting their properties and possibilities of application. Evaluation of the effects of the silicone liquid rubber to formulations of chitosan and alginate membranes both with and without silver-containing antimicrobial agent, to improve the overall mechanical properties of the dressings. It found that membranes containing the silicone rubber had a more homogeneous appearance and adequate flexibility and adhesiveness, increasing in tensile strength, both with and without the antimicrobial agent. In addition, the membranes without the antimicrobial agent resulted in a decrease in absorption of all physiological solutions tested. Development chitosan/gelatin composite films embedded with various amounts of wool nanoparticles. In conclusion, it was found that incorporation of wool nanoparticles into chitosan/gelatin composite led to a reduction in swelling, moisture content, dissolution degree and degradation rate of the films. However, tensile strength and elongation at break decreased upon loading the films with wool nanoparticles. films the biodegradable synthetic polymer poly (butylene adipate-co-terephthalate) (PBAT), concluding that the incorporation of saturated fatty acids until 12 carbon atoms reduces the permeability to water vapor and improves the mechanical properties of films made of starch, glycerol, and PBAT produced by extrusion, contributing to the formation of a cohesive and homogeneous polymer matrix. plasticizer sorbitol maltitol plasticize polyol
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