添加MoO3对WO3薄膜气相变色的影响

Zenghai Zhang, Guang-ming Wu, G. Gao, Jiandong Wu, W. Feng
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引用次数: 2

摘要

以PdCl2为催化剂制备的纯氧化钨薄膜具有明显的气致变色性能。本文采用溶胶-凝胶法将MoO3掺杂到WO3溶胶中。利用FT-IR,差示扫描量热计(DSC-TG)和紫外可见光谱分析了该材料作为智能窗口的复合溶胶,薄膜和光学性质。FT-IR表明,该化合物出现了不同于纯WO3或MoO3的新的特征吸收带。DSC-TG显示了温度从50℃上升到800℃期间的相变。复合薄膜在着色响应时间、着色程度、着色漂白循环利用、非单色气致变色效果等方面均有较好的表现。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Influence of MoO3 addition on the gasochromism of WO3 thin films
Pure tungsten oxide thin films apparently show gasochromic performance, based on PdCl2 catalyst. In this paper, adulteration of MoO3 into WO3 sol has been achieved via sol-gel method. FT-IR, Differential Scanning Calorimeter (DSC-TG) and Uv-visible Spectroscopy have been used to analysis the compound sols, films and optical properties for the use of this material as smart windows. FT-IR shows that for the compound, new characteristic absorption bands arise, which is different from pure WO3 or MoO3. DSC-TG shows the phase change during the temperature ascending from 50 to 800°C. The compound thin films performs relatively well in coloring response time, colored extent, coloring-bleaching recycling and gasochromic effect with non-unicity color.
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