大气等离子体处理SiO2纳米颗粒制备环氧树脂基纳米复合材料的局部放电特性

W. Yan, B. T. Phung, Z. J. Han, K. Ostrikov, T. Blackburn
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引用次数: 4

摘要

由于聚合物分子和纳米颗粒之间的大界面面积改变了复合材料的宏观介电特性,因此将纳米级颗粒掺入基础聚合物物质中可以获得良好的绝缘性能。在制备纳米复合材料之前,采用常压辉光放电氦等离子体对硅烷接枝的SiO2纳米颗粒进行了表面等离子体处理。改性后粒子的表面能有所提高。分别采用未经处理和处理过的纳米颗粒制备了环氧树脂/SiO2纳米复合材料。从抗局部放电性能和击穿强度两方面评价了纳米复合材料的绝缘性能。测试结果表明,与纯环氧树脂样品相比,未经处理和等离子体处理的纳米填料的PD水平明显降低。从而提高了纳米复合材料的电耐久性。在纳米复合材料样品中也检测到更高的PD起始和介电击穿强度。在纳米复合材料的PD水平趋势中观察到梳状光谱。虽然等离子体处理的纳米颗粒样品具有更高的PD密度,但耐久性明显强于未经处理的SiO2样品。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Partial discharge characteristics of epoxy resin-based nanocomposites fabricated with atomospheric plasma treated SiO2 nanoparticles
Favourable insulation properties can be obtained by the incorporation of nano-dimension particles into base polymer substances as the resultant large interface area between polymer molecules and nanoparticles alters the macro dielectric characteristics of the composite material. In this study, surface plasma treatment was carried out using atmospheric pressure glow discharge Helium plasma on silane-grafted SiO2 nanoparticles before the fabrication of the nanocomposite. The surface energy of the particles was increased after such modification. Epoxy resin/SiO2 nanocomposites were fabricated by employing untreated and treated nanoparticles respectively. Insulation performances of the nanocomposites were evaluated in terms of the resistance against partial discharge (PD) and the breakdown strength. Test results showed that the PD levels of the nanocomposites, both with untreated and plasma treated nano-fillers, were noticeably reduced compared to that of the pure epoxy resin sample. As a result, the electrical endurance of nanocomposite was improved. A higher PD inception and dielectric breakdown strength were also detected in nanocomposite samples. A comb-like spectrum was observed in the PD level trend of nanocomposites. Although the sample with plasma treated nanoparticles had a higher PD density, the endurance was noticeably reinforced over the one with the untreated SiO2.
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