ZSM-5沸石制备多通道催化剂单体及表征

Sharifah Noor Munirah S. M Yunus, K. Ismail, K. Hamid, R. Alias, M. Musa, Muhd Hafiz Ramley, Dicky Zulkainey Abd Aziz
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引用次数: 0

摘要

催化裂化是一种从植物油中提高生物燃料产量的新发明。目前,催化裂化反应是在实验室反应器中放置的粉末催化剂上进行的,这些催化剂很难再生。本研究的目的是制备和表征一种结构催化剂,称为多通道催化剂单体,用于棕榈油转化为液体燃料的催化裂化,涉及表面形貌,BET表面积和结晶度。以编织不锈钢丝网(WSSWM)作为多通道催化剂的整体基片,采用浸浆涂覆技术在其表面涂覆沸石催化剂。ZSM-5分子筛粉作为催化剂,硅铝摩尔比(SiO2/Al2O3)为50。涂层后的WSSWM在室温下保存12小时,然后进行干燥和热处理,以确保涂层牢固地附着在丝网表面。采用氮吸附、x射线衍射(XRD)和扫描电镜(SEM)对结构催化剂的BET比表面积、晶体形貌和表面形貌进行了表征。对催化剂的性能分析表明,该催化剂具有作为棕榈油催化裂化催化剂的应用潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation and characterization of multichannel catalyst monolith using ZSM-5 zeolite
Catalytic cracking is an invented process to improve the yield of biofuels from vegetable oil. Currently, catalytic cracking reaction is carried out on the powder catalyst placed in the lab reactor where these catalysts are difficult to regenerate. The purpose of this study is to prepare and characterize a structured catalyst termed as multichannel catalyst monolith for catalytic cracking of palm oil conversion to liquid fuels with respect to surface morphology, BET surface area and crystallinity. Woven Stainless Steel Wire Mesh (WSSWM) was used as a multichannel catalyst monolith substrate, which is then coated with a zeolite catalyst by using dip-slurry coating technique. The ZSM-5 zeolite powders were used as a catalyst with silica-alumina mole ratio (SiO2/Al2O3) of 50. The coated WSSWM was kept at room temperature for 12 hours, followed by drying process and thermal treatment to ensure the coating layer attached strongly onto wire mesh surface. The BET surface area, crystalline, and surface morphology of structured catalysts were examined by Nitrogen Adsorption, X-ray Diffraction (XRD), and Scanning Electron Microscope (SEM), respectively. Analysis of the catalyst characterization indicates its potential to be applied as a catalyst in catalytic cracking of palm oil.
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