基于氯丁橡胶和废弹性体的低碳足迹复合材料

M. Georgescu, M. Sönmez, L. Alexandrescu, Mihaela Nițuică (Vilsan), M. Stelescu, D. Gurau, Denis-Andrei Drușan, Ana-Maria Ciobanu, C. Chelaru
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引用次数: 0

摘要

本文的目的是根据4R原则(减少、再利用、回收和回收),通过将弹性体和塑体转化为具有附加值的原材料并将其整合到不同的行业中,处理弹性体和塑体的消费后和技术废物。这将导致有关获得具有不同废物含量(10- 50% wt%)的新型可生物降解复合材料的新加工概念的发展。该复合材料以氯丁橡胶为基础,添加了45目的消费后再生橡胶颗粒、生态增强材料、活性填料、增塑剂、硫化剂、抗氧化剂。为了提高弹性体废料的相容性和相互作用水平,对弹性体废料进行了深冷研磨和油酸钾功能化处理。橡胶废料作为填充材料,导致低碳足迹的复合材料和较低的质量。考察了复合材料的拉伸强度、撕裂强度、弹性、硬度、耐磨性、熔体流动指数和形态研究(FT-IR),以确定其在各个应用领域的可行性。将废物(低温碾磨和功能化)转化为具有附加值的新产品,将显著改善原材料的生命周期和废物的可持续利用,有助于增加可持续性,提高生态效率和经济效率,减少对环境的碳足迹。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Low Carbon Footprint Composite Based on Chloroprene Rubber and Elastomer Waste
The aim of the paper consists in the treatment of post-consumer and technological waste of elastomers and plastomers, according to the 4R principle (reduction, reuse, recycling and recovery) by transforming them into raw materials with added value and integrating them into different industries. This will lead to the developing of new processing concepts regarding obtaining new biodegradable composite materials, with various waste contents (10-50 wt%). The composite is based on chloroprene rubber, and added post-consumer recycled rubber particles, with size of 45 mesh, eco-reinforcing material, and active fillers, plasticizers, vulcanizing agents, antioxidants. In order to enhance the compatibility and their level of interaction, the elastomer waste was finely ground (cryogenic mill) and functionalized with potassium oleate. Rubber waste acts as a filling material which leads to lower carbon footprint of the composite and lower mass. Tensile, tear strength, elasticity, hardness, abrasion resistance, melt flow index and morphological study (FT-IR) of those composites were examined in order to determine their viability in various application areas. The transformation of waste (cryogenically ground, and functionalized) into new products with added value will lead to remarkable improvements in the life cycle of raw materials and the sustainable use of this waste, contributing to increasing sustainability, improving eco-efficiency and economic efficiency and reducing the carbon footprint on the environment.
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