塑料作为一种潜在能源:综述

Amrita Soni
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摘要

塑料发明已经有一个世纪了,我们在日常生活中以各种可能的方式广泛使用它。一般的塑料需要数千年的时间才能完全分解,而生物降解塑料则需要将近一年的时间才能完全分解,但是在适当的阳光(紫外线)的有利条件下,它的长链键会断裂,并且需要高压。来自各种来源的塑料,如家庭用品,垃圾中含有低密度聚乙烯(LDPE),聚对苯二甲酸乙二醇酯(PET),聚丙烯(PP),这些塑料在热解下可以分解成较少数量的碳链(烷烃),并可以转化为可燃油,燃烧时燃烧干净且无煤烟。另一种将它们转化为燃料的方法是使用其他一些有助于聚合物链容易分解的材料,例如用通常具有低热值的低品位煤热解塑料。第二种选择是将聚合物与低等级重含硫量的油结合起来,在一定的温度和压力下,用一些合适的催化剂将硫从酸油中注入到聚合物的长链中,从而分解它们。说到可生物降解的塑料,它们可以通过微藻转化为燃料,微藻在处理后会将其转化为固体燃料,某些细菌在食用时会释放出某些可燃气体,可以用作沼气厂的沼气。这篇综述的目的是强调塑料转化为燃料的各种过程。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Plastics as A Potential Source of Energy: A Review
It’s almost been a century since the invention of plastic we all are using it extensively in all possible way in our everyday life. It takes thousands of years for typical plastic and almost one year for biodegradable plastic for complete breakdown, but under favorable condition with proper sunlight (ultraviolet light) which breaks its long chain bonds and requires high pressure. Plastics from various sources like household items, trash contains low density polyethylene (LDPE), polyethylene - terephthalate (PET), polypropylene (PP) which under pyrolysis can be broken down into smaller number of carbon chain (alkanes) and can be converted to flammable oils which will burn with clean and non - sooty flame. Other method of converting them to fuel is by using some other materials which will help polymer chain to breakdown easily such as pyrolysis of plastics with low grade coal which is generally having low calorific value. Second option could be by combining polymers with low grade heavy Sulphur content oils which under certain temperature and pressure with some suitable catalyst which will infuse Sulphur from sour oil to long chains of polymers thus breaking them down. Talking about biodegradable plastic they can be converted to fuel by microalgae which will convert it to solid fuel upon treatment and certain bacteria which upon eating releases certain flammable gases and can be used as a biogas in biogas plant. This review aims on highlighting the various process for conversion of plastics to fuel.
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