{"title":"橙皮提取物介导银纳米流体作为X80钢在模拟油田阻垢剂中的缓蚀剂","authors":"E. Ituen, Chukwudurom Dim, E. Boekom","doi":"10.30564/jmmr.v4i1.3621","DOIUrl":null,"url":null,"abstract":"Silver nanofluid was prepared by bio-reduction reaction between orange peels extracts (OPE) and silver nitrate and characterized by spectroscopic and microscopic techniques. Colloidal nanoparticles of sizes between 40 – 50 nm and spherical shape were obtained. The nanofluid was applied as anticorrosion additive to inhibit corrosion of X80 steel in simulated oilfield scale dissolver solution (1.0 M HCl) at various temperatures. The nanofluid (OPE-AgNPs) was 98.9 % and 84.3 % efficient at 30 ºC and 60 oC respectively as determined by weight loss measurement. In comparison with OPE, OPE-AgNPs shows better corrosion inhibition and higher resistance to thermal degradation. Some kinetic and thermodynamic models were used to characterize the inhibition process. OPE-AgNPs could be optimized and used as alternative anticorrosion additive for scale dissolution liquor in the industry.","PeriodicalId":232294,"journal":{"name":"Journal of Metallic Material Research","volume":"62 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Orange Peel Extract Mediated Silver Nanofluid as Corrosion Inhibitor for X80 Steel in Simulated Oilfield Scale Dissolver\",\"authors\":\"E. Ituen, Chukwudurom Dim, E. Boekom\",\"doi\":\"10.30564/jmmr.v4i1.3621\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Silver nanofluid was prepared by bio-reduction reaction between orange peels extracts (OPE) and silver nitrate and characterized by spectroscopic and microscopic techniques. Colloidal nanoparticles of sizes between 40 – 50 nm and spherical shape were obtained. The nanofluid was applied as anticorrosion additive to inhibit corrosion of X80 steel in simulated oilfield scale dissolver solution (1.0 M HCl) at various temperatures. The nanofluid (OPE-AgNPs) was 98.9 % and 84.3 % efficient at 30 ºC and 60 oC respectively as determined by weight loss measurement. In comparison with OPE, OPE-AgNPs shows better corrosion inhibition and higher resistance to thermal degradation. Some kinetic and thermodynamic models were used to characterize the inhibition process. OPE-AgNPs could be optimized and used as alternative anticorrosion additive for scale dissolution liquor in the industry.\",\"PeriodicalId\":232294,\"journal\":{\"name\":\"Journal of Metallic Material Research\",\"volume\":\"62 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Metallic Material Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.30564/jmmr.v4i1.3621\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Metallic Material Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.30564/jmmr.v4i1.3621","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
摘要
以橘子皮提取物(OPE)和硝酸银为原料,采用生物还原法制备了银纳米流体,并用光谱和显微技术对其进行了表征。得到了粒径在40 ~ 50 nm之间的球形胶体纳米颗粒。将纳米流体作为防腐蚀添加剂,在模拟油田水垢溶解液(1.0 M HCl)中不同温度下抑制X80钢的腐蚀。通过失重测量,纳米流体(OPE-AgNPs)在30℃和60℃时的效率分别为98.9%和84.3%。与OPE相比,OPE- agnps具有更好的缓蚀性和耐热降解性。采用动力学和热力学模型对缓蚀过程进行了表征。OPE-AgNPs可作为工业溶垢液的替代防腐添加剂。
Orange Peel Extract Mediated Silver Nanofluid as Corrosion Inhibitor for X80 Steel in Simulated Oilfield Scale Dissolver
Silver nanofluid was prepared by bio-reduction reaction between orange peels extracts (OPE) and silver nitrate and characterized by spectroscopic and microscopic techniques. Colloidal nanoparticles of sizes between 40 – 50 nm and spherical shape were obtained. The nanofluid was applied as anticorrosion additive to inhibit corrosion of X80 steel in simulated oilfield scale dissolver solution (1.0 M HCl) at various temperatures. The nanofluid (OPE-AgNPs) was 98.9 % and 84.3 % efficient at 30 ºC and 60 oC respectively as determined by weight loss measurement. In comparison with OPE, OPE-AgNPs shows better corrosion inhibition and higher resistance to thermal degradation. Some kinetic and thermodynamic models were used to characterize the inhibition process. OPE-AgNPs could be optimized and used as alternative anticorrosion additive for scale dissolution liquor in the industry.