NLO效应在聚合物中的热稳定性

G. Yang
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引用次数: 1

摘要

通过电光系数测量和热释电热分析,研究了不同聚合物在电晕或电子束极化后的非线性光学效应及其热稳定性。测试材料是分散红1 (DR1)和聚甲基丙烯酸甲酯(PMMA)的主-主聚合物,PMMA具有DR1侧基的侧链聚合物,具有DR1侧基的侧链苯乙烯-马来酸酐共聚物,以及交联侧链聚合物Red- acid Magly。实验结果表明,电子束极化样品的NLO效应与电晕极化样品相当,但现阶段电子束极化材料的热稳定性仍然较低。讨论了电子束极化样品热稳定性较低的原因和克服这一问题的可能途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Thermal stability of NLO effects in polymers
Nonlinear optical (NLO) effects and their thermal stability in different polymers after corona or electron-beam poling are investigated by electro-optical coefficient measurement and by pyroelectric thermal analysis. Tested materials are a guest-host polymer of Disperse Red 1 (DR1) and polymethylmethacrylate (PMMA), a side-chain polymer of PMMA with DR1 side groups, a side-chain styrene-maleic anhydride co-polymer with DR1 side groups, and a cross-linked side-chain polymer Red-Acid Magly. The experimental results indicate that NLO effects in electron-beam poled samples are comparable with those in corona poled samples, while the thermal stability of the electron-beam poled materials is still low in the present stage. The reasons for the lower thermal stability of electron-beam poled samples and a possible way to overcome it are discussed.
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