时间-温度漂移原理和阶梯等温法在etfe薄膜上的应用

Jonas Hornig, Karsten Moritz, Benjamin König
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引用次数: 0

摘要

时间-温度变换(TTS)原理在塑料材料,特别是粘弹性聚合物上的应用已经有很长一段时间了。该原理描述了参数时间(由应变率体现)和温度对聚合物力学行为(应力、应变、刚度、强度值)的影响。对于允许应用TTS的聚合物,这两个参数显然对分子链具有反比影响,因此对材料的机械性能也具有反比影响。TTS允许这两个参数的转换,而且还可以预测尚未测试过的范围内的机械行为。对于etfe箔,TTS是其在建筑实践中适用性的原因,这意味着在低应变率和低温的雪荷载下以及在高应变率和高温的风荷载下。在两种载荷情况下,材料的刚度和强度值保持在可接受的范围内。TTS原理于2007年首次应用于ETFE薄膜。然后,利用单轴短期拉伸试验形式的广泛参数研究的评估来推导主曲线,并制定用于ETFE薄膜[2]的TTS数学描述的arrhenius函数。该函数首次对ETFE的力学行为进行了预测
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Time-Temperature-Shift Principle and Stepped Isothermal Method applied on ETFE-Foils
The application of the time-temperature shift (TTS) principle on plastic materials, especially viscoelastic polymers, has been known since a long time. This principle describes the influences of the parameters time (embodied by the strain rate) and temperature on the polymer’s mechanical behaviour (stress, strain, stiffness, strength values). In case of polymers that allow the application of the TTS both parameters obviously have an inversely proportional influence on the molecular chains and, therefore, on the mechanical properties of the material. The TTS allows the conversion of both parameters, but also the prediction of the mechanical behaviour in ranges that haven’t been tested. In case of ETFE-foils the TTS is the reason for their applicability in the building practice that means under snow loads with low strain rates and low temperatures and under wind loads at high strain rates and high temperatures. In both load case scenarios the materials stiffness and strength values keep in acceptable ranges. The TTS principle has been applied on ETFE foils in 2007 the first time [1]. The evaluation of an extensive parameter study in form of uniaxial short-term tensile tests was then used to derive a master curve and to formulate an ARRHENIUS-function for the mathematical description of the TTS of ETFE foils [2]. This function allowed the first time to predict the mechanical behaviour of ETFE
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