{"title":"修正关联形式框架下的吸附热力学","authors":"D. Saulov, V. Rudolph, A. Klimenko","doi":"10.2174/1874396X01105010011","DOIUrl":null,"url":null,"abstract":"A new thermodynamic model of adsorption of gas mixtures on microporous adsorbents is suggested. The model is based on Vacancy Solution Theory, while the recently proposed Modified Associate Formalism is used for adsorbed phase. The proposed model allows prediction of co-adsorption isotherms based on fitting those for pure gases.","PeriodicalId":238681,"journal":{"name":"The Open Thermodynamics Journal","volume":"5 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2011-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Adsorption Thermodynamics in the Framework of the Modified Associate Formalism\",\"authors\":\"D. Saulov, V. Rudolph, A. Klimenko\",\"doi\":\"10.2174/1874396X01105010011\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new thermodynamic model of adsorption of gas mixtures on microporous adsorbents is suggested. The model is based on Vacancy Solution Theory, while the recently proposed Modified Associate Formalism is used for adsorbed phase. The proposed model allows prediction of co-adsorption isotherms based on fitting those for pure gases.\",\"PeriodicalId\":238681,\"journal\":{\"name\":\"The Open Thermodynamics Journal\",\"volume\":\"5 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2011-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Open Thermodynamics Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/1874396X01105010011\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Thermodynamics Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1874396X01105010011","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Adsorption Thermodynamics in the Framework of the Modified Associate Formalism
A new thermodynamic model of adsorption of gas mixtures on microporous adsorbents is suggested. The model is based on Vacancy Solution Theory, while the recently proposed Modified Associate Formalism is used for adsorbed phase. The proposed model allows prediction of co-adsorption isotherms based on fitting those for pure gases.