LiYbxY1-xF4单晶中Gd3+-Yb3+交换作用

L. Misiak
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引用次数: 0

摘要

liybxy1 - 144中最近和次近邻的Gd3+-Yb3+交换相互作用随Yb3+离子浓度x呈抛物线型增加。Gd3+- yb3 +交换相互作用在x = 0.6 ~ 1.0范围内对x敏感,而在x- = 0.1 ~ 0.5范围内基本不变。当x为0.1 ~ 1时,估计的Gd3+-Yb3+交换相互作用常数分别在0.5 ~ 2.8 Ghz范围内。这些交换作用常数随温度的降低而增大。结果与用分子场模型估计的结果相当。在顺磁稀释LiYbxY1-xF4晶体中,平均Gd3+-Yb3+ pari交换相互作用常数为0.33 Ghz。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Gd3+-Yb3+ exchange interactions in LiYbxY1-xF4 single crystals
The evaluated Gd3+-Yb3+ exchange interactions over the nearest and the next-nearest neighbors in LiYbxY1-1F4 are found to increase in parabolic manner with x, the concentration of Yb3+ ions. The Gd3+-Yb3+ exchange interactions are sensitive to x in the range x equals 0.6-1.0, while they are almost constant in the range x- equals 0.1-0.5. The estimated Gd3+-Yb3+ exchange interaction constants are in the range 0.5-2.8 Ghz for x from 0.1 to 1, respectively. These exchange interaction constants are increased with lowering temperature. The results are comparable to those of estimated using the molecular-field model. The average Gd3+-Yb3+ pari exchange interaction constant is determined to be 0.33 Ghz in paramagnetically diluted LiYbxY1-xF4 crystals.
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