磁性材料修复水体氮污染的研究

G. Zhu, Junming Chen
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摘要

天然有机物影响水环境安全,对人类健康构成潜在威胁,长期以来一直被视为评价水处理性能的关键指标。溶解有机氮是NOM之一,它产生的一些消毒副产物比那些碳基材料毒性更大。混凝是饮用水净化的关键装置,受到了广泛的关注。然而,常规絮凝技术对DON的去除效果较差,必须寻求更有效的改进措施。常规絮凝剂与有机聚合物联合使用可在一定程度上提高处理效率,强化混凝也可提高DON去除率,但其DON去除率仍不理想。目前,对絮凝去除DON的研究还缺乏系统的研究。虽然取得了一些成果,但絮凝剂的制备技术与高效去除水中DON的目标还有很大的差距。对于工业废水二次出水的处理,有研究表明,Fe3O4的使用主要起到加速分离的作用,但吸附效果不佳。而氨基功能化Fe3O4的协同絮凝作用对去除水中的水蛋白、多糖和腐植酸有较好的效果,可满足水质排放标准,减少絮凝剂用量。上述结果表明,功能纳米颗粒材料对提高吸附絮凝性能具有重要意义。因此,磁性纳米颗粒的功能修饰起着重要的作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Developing Magnetic Material for Remediation of Aquatic Nitrogen Pollution in Water Facilities
Natural organic matter affect water environmental security and posed a potential threat to human health, and thus it has long been considered as a key index to evaluate water treatment performance. Dissolved organic nitrogen is one of the NOM, which produces some disinfection byproducts having more toxic than those carbon-based materials. Coagulation is a key unit of drinking water purification and has received wide attention. However, conventional flocculation technology on removal of DON is so poor that we have to seek more effective improving measurement. The combined use of conventional flocculant and organic polymer can improve treatment efficiency to a certain extent, and enhanced coagulation can also improve the DON removal rate, but their DON removal performance is still not dreamful. At present, there is a lack of systematic research on flocculation to remove DON. Although some achievements have been made, there is still a big gap between the preparation technology of flocculant and the goal of efficient removal of DON in water.For treatment of secondary effluent of industrial wastewater, some studies show that the use of Fe3O4 mainly has the effect of accelerating separation, but the adsorption effect is not good. However, with the synergistic flocculation of amino functionalized Fe3O4 it has a good effect on removing water protein, polysaccharide and humic acid, which can meet the water quality discharge standard and reduce the dosage of flocculant. The above results show that functional nanoparticle materials are of great significance to improve the adsorption and flocculation performance. Therefore, the functional modification of magnetic nanoparticles plays an important role.
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