Julia Zwara, Magdalena Miodyńska, E. Grabowska, A. Zaleska-Medynska
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引用次数: 0
摘要
在最近的过去,污染已经成为对我们周围的世界产生负面影响的主要问题。人们正在积极寻求能够清除它们的环境友好的方法和解决办法,以及能够通过获取替代能源来进行化学还原的过程。可用于这种工艺的光催化剂之一是Ag3PO4。此外,与TiO2 (3.2 eV)相比,所提出的半导体具有较窄的能隙(2.48 eV),这可能表明其在可见光范围内受辐照影响具有较高的光活性(Chen, Dai, & Wang, 2015;李、陈、王、腾,2014;Wan et al., 2015)(Chen et al., 2015;Wan et a., 2015;Li等人,2014)。光催化激发机制也可以通过用贵金属纳米颗粒修饰半导体表面来辅助。到目前为止,有关Pt纳米颗粒在Ag3PO4表面的应用的文献尚未见,因此本研究开发了一种新的修饰方法。同时,这项工作的目的是评估沉积在半导体表面的金属量对其性质和光催化活性的影响。
Increase of photocatalytic activity of Ag3PO4 by surface modification with Pt nanoparticles
In the recent past, pollution has become the main problem that has a negative impact on the world around us. Environmentally friendly methods and solutions that allow for removal them are intensively sought and also processes enabling to their chemical reduction by acquire alternative energy sources. One of the photocatalysts that can be used in such processes is Ag3PO4. What's more, the proposed semiconductor is characterized by a narrow energy gap (2.48 eV) in contrast to TiO2 (3.2 eV), which may indicate its high photoactivity under the influence of irradiation in the visible range (Chen, Dai, & Wang, 2015; Li, Chen, Wang, & Teng, 2014; Wan et al., 2015)(Chen et al., 2015; Wan et a., 2015; Li et al., 2014). The photocatalytic excitation mechanism can also be aided by surface modification of the semiconductor with noble metal nanoparticles. Until now, information on the application of Pt nanoparticles to the surface of Ag3PO4 has not been found in the literature on the subject, therefore a new modification method has been developed in this study. At the same time, the aim of the work was to assess the impact of the amount of metal deposited on the surface of the semiconductor on its properties and photocatalytic activity.