过冷甘油-水溶液的介电性能

1987 Ninth International Conference on Conduction and Breakdown in Dielectric Liquids Pub Date : 1987-07-01 DOI:10.1109/14.7335

J. Huck, G. Noyel, L. Jorat

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引用次数: 27

摘要

小浓度的氢键杂质，如甘油，容易破坏纯水的氢键结构，并阻止结晶。外推得到的性质肯定是纯水的性质:Tg与玻璃冰的玻璃化转变温度很符合;εs(T)表示RICE模型预测的变化。我们的结果支持过冷和非晶固体水之间状态连续性的观点。

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Dielectric properties of supercooled glycerol-water solutions

Little concentrations of a hydrogen-bonding impurity as glycerol, tend to break the hydrogen bonded structure of pure water and to prevent crystallization. The properties obtained by extrapolation are certainly those of pure water: Tg is in good agreement with the glass transition temperature of vitreous ice; εs(T) shows the variations predicted by the model of RICE. Our results support the idea of a continuity of states between supercooled and amorphous solid water.

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1987 Ninth International Conference on Conduction and Breakdown in Dielectric Liquids

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