电晕带电和直流场极化PVDF薄膜的热释电响应和介电行为

B. Hilczer, J. Kułek
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引用次数: 0

摘要

研究了PVDF薄膜在低直流电场和电晕带电条件下的介电弛豫和热释电响应。电晕带电PVDF膜的热释电系数p与光调制频率f(从十几赫兹到几千赫)的关系很弱。当正侧被照亮时,在直流磁场中极化的薄膜制成的隔膜也发现了同样的情况,然而,当在极化期间被接地的侧被照亮时,在p(f)中观察到低频异常。极化诱导的补偿电荷堆积在半结晶聚合物的结晶相中,影响了在MHz频率范围内的/spl β /-弛豫。
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Pyroelectric response and dielectric behaviour of corona charged and dc field polarized PVDF films
Dielectric relaxation and pyroelectric response of PVDF films poled in low dc field and corona charged was studied. Pyroelectric coefficient p of corona charged PVDF diaphragm is weakly dependent on light modulation frequency f from a dozen of Hz to a few kHz. The same is found for diaphragms made of film poled in dc field when the side being positive is illuminated, however, a low-frequency anomaly in p(f) is observed when the side being grounded during poling is illuminated. Poling-induced compensating charges, piled up at the crystalline phase of a semicrystalline polymer, influence the /spl beta/-relaxation in MHz frequency range.
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