ZnO对Sb2O3-PbO-ZnO体系物理性能的影响

R. Abdi, M. Nouadji, M. Poulain
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引用次数: 0

摘要

研究了以氧化锑Sb $_{\mathbf {2}} \mathbf {O} _{\mathbf {3}}$为基础的玻璃体体系。报道了Sb $_{\mathbf {2}} \mathbf {O} _{\mathbf {3}}$ -PbO-ZnO三元体系中玻璃形成的极限。差示扫描量热法的热测量表明,Tg在300℃以上。总的趋势是Tg随氧化锌含量的增加而增加。研究了ZnO取代对(80 $-\textbf{x}$)Sb2O3-20PbO-xZnO体系的光学和物理性能的影响:随着氧化锌浓度的增加,维氏显微硬度、杨氏模量增加。密度呈反比关系。紫外线透射率稳定在75左右% and extended IR transmission is obtained. This behavior is discussed in relation to structural hypothesis.
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of ZnO on physical properties of Sb2O3-PbO-ZnO system
Vitreous systems based on antimony oxide Sb$_{\mathbf {2}} \mathbf {O} _{\mathbf {3}}$ have been investigated. The limits for glass formation are reported in the Sb$_{\mathbf {2}} \mathbf {O} _{\mathbf {3}}$-PbO-ZnO ternary system. Thermal measurements implemented by differential scanning calorimetry show that Tg is above 300°C. As a general trend, Tg increases with zinc oxide content. The influence of the ZnO substitution on the optical and physical properties has been studied in the (80$-\textbf{x}$)Sb2O3-20PbO-xZnO system: Vickers micro-hardness, Young’s modulus increase as zinc oxide concentration increases. An inverse dependence is observed for density. U.V. transmission stabilized around 75% and extended IR transmission is obtained. This behavior is discussed in relation to structural hypothesis.
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