纳米管植物吸附剂在石油吸附净化过程中的应用技术

L. Krichkovskaya, E. Elnaggar, V. Dubonosov
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摘要

本文指出了植物油吸附提纯的重要性,认为这是最重要的技术阶段。指出了乌克兰国内吸附剂范围科学发展的不足。葵花籽皮纳米管植物吸附剂可将未精制葵花籽油和大豆油的部分质量参数提高到成品油的标准值。本文分析了一些文献资料中热处理后的吸附材料(含碳、天然、纤维和从农业废弃物-榛果中获得的吸附剂)的主要特性。考虑了主要吸附性能;尊严;的局限性。研究了温度在150 ~ 600℃范围内对植物原料热解产率及炭化产物性能的影响。所有实验中物料在该过程最终温度下的暴露时间相同,均为1 h。通过对实验数据的分析,我们可以得出结论,温度是影响初始植物物料炭化过程的主要因素。无论热解气氛如何,植物原料的产率都随着温度的显著升高而降低。目前,工业生产吸附剂的主要原料在许多研究中都是有机物——木材、化石煤、泥炭、农业原料加工后的残余物,因为它们成本低、用量大。解决了在植物原料的基础上制造吸附剂的问题,并在其组成中加入水合富勒烯,解决了制造吸附剂的问题和环境问题,因为废物并不总是能找到有用的应用。水合C60的水溶液浓度,快速的C60FWS,分子-胶体体系和球形分形团簇,其结构单元为微亲水、高亲水的超分子络合物,分子可折叠成)24水合的富勒烯C60 (C60HyFn)。水合培养被设置在它自己的有序的,结构上不均匀的水中间,其中化学过程的直接性和动力学可见,为了清洁它是必要的洗涤。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
TECHNOLOGICAL ASPECTS OF APPLICATION OF THE PHYTOSORBENT WITH NANOTUBES IN THE PROCESS OF ADSORPTIVE OIL PURIFICATION
In the present article importance of adsorptive purification of vegetable oils is shown as the most responsible technological stage. Insufficiency of scientific developments in the scope of domestic sorbents in Ukraine is pointed out. The phytosorbent with nanotubes from sunflower peel improving some quality parameters of non-refined sunflower and soybean oils to standard values for refined oils has been offered. Some literature data on the main characteristics of a number of sorption materials (carbonaceous, natural, fibrous, and sorbents obtained from agricultural waste - Corylus avellana Lambert nuts) as a result of heat treatment are analyzed. The main sorption properties are considered; dignity; limitations. The effect of temperature on the productivity of pyrolysis of plant raw materials and the properties of the resulting carbonizates in the temperature range 150-600 °C was investigated. The duration of exposure of materials at the final temperature of the process in all experiments was the same and amounted to 1 h. Analysis of the experimental data allows us to conclude that temperature is the main factor affecting the process of carbonization of the initial plant material. Regardless of the pyrolysis atmosphere, the yield of the product from plant raw materials decreases with a significant increase in temperature. At present, the main raw material for the industrial production of adsorbents is in many studies organic substances - wood, fossil coal, peat, remnants of the processing of agricultural raw materials due to their low cost and large amount. Solving the problem of creating sorbents based on plant raw materials with the inclusion of hydrated fullerenes in their composition solved the problem of creating sorbents and environmental problems, since the waste did not always find a useful application. Concentration of water solution of hydrated C60, fast C60FWS, є molecular-coloidal systems and spherical fractal clusters, structural unit of which is micro-hydrophilic, high-hydrophilic supramolecular complex, molecules can be folded to fit into ) 24-hydration of fullerene C60 (C60HyFn). The hydrated cultivation is set in its own well-ordered, structurally heterogeneous watery middle, in which the directness and kinetics of chemical processes are seen in such, that it is necessary to be washed in order to clean.
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