以豆荚壳为生物催化剂的豆荚生物柴油工艺优化

O. E. Ogundahunsi, B. Ogunsina, E. Aransiola
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引用次数: 0

摘要

本研究以未充分利用的kariya油籽为原料,在kariya豆荚壳生物催化剂的存在下,利用乙醇生产生物柴油。采用索氏溶剂萃取法提取油。采用响应面法的中心复合设计(CCD)研究了山茱萸籽油的酯交换反应。基于CCD实验设计,对反应温度(65、70、85℃)、反应时间(2、3、4 h)、乙醇/kariya油摩尔比(8:1、10:1、12:1)等工艺因素进行建模。测定了所制备的生物柴油及其与汽油柴油的混合物的燃料性能。山茱萸油的平均提取率为32.55 wt. %。结果表明,在最佳条件下,生物柴油的产率为94.41 wt.%;温度为75℃,时间为2 h,乙醇:油摩尔比为10:1,催化剂负载为5 wt.%。生产的生物柴油及其混合物的物理化学和燃料特性完全符合美国材料测试协会(ASTM D6751)的标准,与汽油柴油相比具有优势。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Kariya Biodiesel Process Optimization Using Kariya Pod-husks Bio-catalyzed
In this study, biodiesel was produced from underutilized kariya oilseed using ethanol in the presence of kariya pod-husks bio-catalyst. The oil used was extracted through the soxhlet solvent extraction approach. Transesterification of kariya seed oil was investigated using Central Composite Design (CCD) of Response surface methodology. Process factors such as reaction temperature (65, 70, and 85oC), reaction time (2, 3, and 4 h), and ethanol/kariya oil molar ratio (8:1, 10:1, and 12:1) were modeled based on CCD experimental design. The fuel properties of biodiesel produced, and its blends with petrol-diesel were determined. The average yield of extracted kariya oil was 32.55 wt. %. Based on the results, biodiesel yield of 94.41 wt.% was obtained at optimal conditions; a temperature of 75oC, time of 2 h, and ethanol: oil mole ratio of 10:1 at catalyst loading of 5 wt.%. The physicochemical and fuel properties of produced biodiesel and its blend were well within American Society for Testing and Materials (ASTM D6751) standard and compared favorably with petrol-diesel.
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