Lilian N. M. Braguin, Caio V. Juvencio da Silva, Larissa O Berbel, I. Costa, M. Saiki
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引用次数: 1
摘要
ISO 5832-1奥氏体不锈钢作为生物材料广泛应用于骨科领域,特别是在植入物的制造中,如骨结构的临时或永久替代。本研究的目的是通过电化学测试在两种不同的溶液中评估用于骨科植入物的ISO 5832-1不锈钢的局部耐腐蚀性。本研究的结果对评估金属植入物的腐蚀具有重要意义,金属植入物可能导致腐蚀产物释放到体液中,从而引起可能的不良生物反应。采用中子活化分析法(NAA)测定了ISO 5832-1不锈钢成分中的化学元素。电化学试验样品用碳化硅纸研磨至4000度,然后用金刚石膏进行机械抛光。在0.90 wt. % NaCl溶液和模拟体液(SBF)溶液中获得了开路电位测量和阳极极化曲线。结果表明,ISO 5832-1不锈钢在模拟体液溶液中具有较高的抗缝隙腐蚀性能,但在氯化物溶液中对这种形式的腐蚀具有较高的敏感性。
A study on corrosion resistance of ISO 5832-1 austenitic stainless steel used as orthopedic implant
The ISO 5832-1 austenitic stainless steel used as biomaterial is largely applied in the area of orthopedics, especially in the manufacture of implants, such as temporary or permanent replacement of bone structures. The objective of this study was to evaluate the localized corrosion resistance of the ISO 5832-1 stainless steel used in orthopedic implants by electrochemical tests in two different solutions. The results of this study are of great interest to evaluate the corrosion of metallic implants that can result in the release of corrosion products into bodily fluids causing possible adverse biological reactions. The determination of the chemical elements in the composition of the ISO 5832-1 stainless steel was performed by neutron activation analysis (NAA). The samples for electrochemical tests were grinded with silicon carbide paper up to #4000 finishing, followed by mechanical polishing with diamond paste. The open circuit potential measurements and anodic polarization curves were obtained in solution of 0.90 wt. % of NaCl and of simulated body fluid (SBF). The results indicated that the ISO 5832-1 stainless steel presented a high resistance to crevice corrosion in simulated body fluid solution but high susceptibility to this form of corrosion in the chloride solution.