Wahb Mahdi, I. Hassan, Amani Kamil, I. Alwan, Marwa M. Hassan, Asmaa A. Alwan, Nizar Mahan
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引用次数: 0
摘要
通过透射电子显微镜(HRTEM)观察,利用伊拉克材料和当地市场上常见的简单装置,制备了直径为4.33 ~ 6.37 nm的氧化锌(量子点)。采用简单的化学工艺,在70℃的温度下,向100 ml c3h90o异丙醇中加入0.4 g醋酸锌结晶,持续搅拌30分钟。研究了添加硫化钠(Na2S)的效果,将0.15 g的重量加入到上段制备的溶液中,然后在磁力搅拌器不断搅拌5小时的作用下加入10 ml的TEA。然后得到白色胶体氧化锌,用6000转/分的离心机分离1小时。产品用蒸馏水和甲醇洗涤,在真空烘箱中干燥7小时,干燥温度为50℃。通过x射线衍射对锌氧化胶体量子点的合成性能进行了研究,结果表明氧化锌颗粒的中心方向为(102)、(110)、(103)、(200)、(112)、(201)、(101)、(100)和(002)。灵敏度结果表明,在光照作用下气体传感效率较高。
Metal Oxide (Quantum Dots) for Gas Sensor Application
The research included the preparation of zinc oxide (Quantum Dots) with a diameter of 4.33- 6.37 nm as indicated in the results of transmissionelectron (HRTEM) microscopy at different points of the colloidal (ZnO Q.Ds) produced using Iraqi materials and simple conventional devices available in the local market. . The manufacturing process was carried out by a simple chemical process by adding 0.4 g of crystallized zinc acetate to 100 ml of isopropyl alcohol C3H 9O with constant stirring for a period of 30 minutes under the influence of 70 oC temperature. The effect of adding sodium sulphide (Na2S) has been studied where the weight (0.15 grams) was added to the previous solution prepared within the above paragraph and then added 10 ml of TEA under the effect of constant stirring using a magnetic mixer for five hours . Then a white colloidal ZnO was obtained and separated using a 6000 rpm centrifuge for only one hour. The product was washed with distilled water and methanol and dried in a vacuum oven for 7 hours at a drying temperature of 50 oC. The results of the synthesis properties of zinc oxidized colloidal quantum dots by X-ray diffraction study showed that zinc oxide granules were centered towards (102), (110), (103), (200), (112), (201), (101), (100) and (002). The sensitivity results showed high efficiency of gas sensing under lighting effect.