未掺杂AlGaN/AlN/GaN异质结构上ta基欧姆触点的电学性能

Yunju Sun, L. Eastman
{"title":"未掺杂AlGaN/AlN/GaN异质结构上ta基欧姆触点的电学性能","authors":"Yunju Sun, L. Eastman","doi":"10.1109/DRC.2006.305141","DOIUrl":null,"url":null,"abstract":"Undoped AlGaN/AIN/GaN Heterostructures Yunju Sun and L. F. Eastman 426 Phillips Hall, Cornell University, Ithaca NY 14853 E-mail: _ du Phone: 607-255-1431/607-342-0651 Fax: 607-255-4742 In order to improve the performance of the HFETs, the electrical characteristics of ohmic contacts formed on top of the heterostructures are extremely important in order to achieve a high transconductance and a high saturation current. Previously, thermally stable low resistance with SiCl4 plasma treatment was achieved using Ti/Al/Mo/Au multilayer ohmic contacts on n-GaN [1]. Its thickness and annealing condition were later optimized based on the electrical performance and edge acuity on Undoped AlGaN/GaN HEMTs structure without any plasma surface treatment [2]. The optimized thickness and annealing condition were Ti/Al/Mo/Au (15 nm/90 nm/40 nm/50 nm) and 800 for less than 30 sec respectively. In order to enhance the sheet charge confinement and improve electron mobility at heterojunction interface, a 10-15 A AlN interbarrier was inserted between AlGaN and GaN [3] HEMTs structure. From the experimental results, it was more difficult to get low contact resistance on Undoped AlGaN/GaN heterostructure with AlN interbarrier based on the same optimized Ti/Al/Mo/Au ohmic metal stack. In this report, in order to reduce the contact resistance, same material structure ( Undoped Al.27Ga.73N 230A/AlN 15A/GaN) was used, and Ta/Ti/Al/Mo/Au as a total of five metal layers with Ti/Al/Mo/Au fixed at 15 nm/90 nm/40 nm/50 nm and with Ta at a thickness of 30, 50, and 75 A respectively were evaporated on it. The electrical performance was also compared with the one using Ta/Ti/Al/Ti/Au metal layers on the same material structure. As shown in Fig. 1, with fixed Ti/Al/Mo/Au overlayers, a transfer resistance as low as 0.105 ohm-mm was obtained with Ta at a thickness of 75 A annealed at a cycle of 700 for 1 min followed by 800 for 20 sec. The transfer resistance increased as the Ta layer thickness decreased from 75 A to 30 A. Since comparing with the ohmic metal stack using Ti (4.33 eV) as a bottom layer, Ta has a lower work function (4.25 eV), it can be beneficial for the formation of low contact resistance. However, there could be a fluctuation of barrier height before the inner metal reaches a thickness that the metallic character of the film has been well established [4], which can be related to the dependence of contact resistance on the thickness of inner thin metal film. In Fig. 1, sheet resistance underneath the metal was also measured by \"end-resistance\" method, and the lowest value is 16.24 ohm/square for the one using 75 A Ta. Fig. 2 and Fig. 3 show the total resistance as a function ofTLM metal spacing with good linear fit (0.9997-0.9999) and I-V characteristics of ohmic contacts (9.5 ptm spacing) after annealing at 700 for 1 min followed by 800 for 20 sec respectively for Ti/Al/Mo/Au and Ti/Al/Ti/Au metal stack with an insertion of Ta as a bottom layer. As we can see, under same annealing condition, the contact resistance is a lot higher using Ti/Al/Ti/Au as overlayers. Higher annealing temperature above 800 can be required to reduce the resistance. The rootmean-square surface roughness after annealing was measured by AFM, as shown in Fig. 4. Ta/Ti/Al/Ti/Au contact has the highest value of surface roughness comparing with those of Ta/Ti/Al/Mo/Au contacts. As shown in Fig.5, the annealed Ta 75A/Ti/Al/Mo/Au contacts also had good edge acuity. The creeping of metal is less than 65 nm.","PeriodicalId":259981,"journal":{"name":"2006 64th Device Research Conference","volume":"15 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2006-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrical Performance of Ta-Based Ohmic Contacts on Undoped AlGaN/AlN/GaN Heterostructures\",\"authors\":\"Yunju Sun, L. Eastman\",\"doi\":\"10.1109/DRC.2006.305141\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Undoped AlGaN/AIN/GaN Heterostructures Yunju Sun and L. F. Eastman 426 Phillips Hall, Cornell University, Ithaca NY 14853 E-mail: _ du Phone: 607-255-1431/607-342-0651 Fax: 607-255-4742 In order to improve the performance of the HFETs, the electrical characteristics of ohmic contacts formed on top of the heterostructures are extremely important in order to achieve a high transconductance and a high saturation current. 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In this report, in order to reduce the contact resistance, same material structure ( Undoped Al.27Ga.73N 230A/AlN 15A/GaN) was used, and Ta/Ti/Al/Mo/Au as a total of five metal layers with Ti/Al/Mo/Au fixed at 15 nm/90 nm/40 nm/50 nm and with Ta at a thickness of 30, 50, and 75 A respectively were evaporated on it. The electrical performance was also compared with the one using Ta/Ti/Al/Ti/Au metal layers on the same material structure. As shown in Fig. 1, with fixed Ti/Al/Mo/Au overlayers, a transfer resistance as low as 0.105 ohm-mm was obtained with Ta at a thickness of 75 A annealed at a cycle of 700 for 1 min followed by 800 for 20 sec. The transfer resistance increased as the Ta layer thickness decreased from 75 A to 30 A. Since comparing with the ohmic metal stack using Ti (4.33 eV) as a bottom layer, Ta has a lower work function (4.25 eV), it can be beneficial for the formation of low contact resistance. 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The rootmean-square surface roughness after annealing was measured by AFM, as shown in Fig. 4. Ta/Ti/Al/Ti/Au contact has the highest value of surface roughness comparing with those of Ta/Ti/Al/Mo/Au contacts. As shown in Fig.5, the annealed Ta 75A/Ti/Al/Mo/Au contacts also had good edge acuity. 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引用次数: 0

摘要

Sun Yunju和L. F. Eastman 426 Phillips Hall, Cornell University, Ithaca NY 14853 E-mail: _ du Phone: 607-255-1431/607-342-0651 Fax: 607-255-4742为了提高hfet的性能,在异质结构顶部形成的欧姆触点的电学特性是非常重要的,以实现高跨导和高饱和电流。以前,利用n-GaN上的Ti/Al/Mo/Au多层欧姆触点实现了SiCl4等离子体处理的热稳定低电阻[1]。然后根据未掺杂的AlGaN/GaN HEMTs结构的电学性能和边缘锐度对其厚度和退火条件进行优化,而无需进行任何等离子体表面处理[2]。优化的厚度和退火条件分别为Ti/Al/Mo/Au (15 nm/90 nm/40 nm/50 nm)和800,退火时间小于30秒。为了增强片电荷约束和提高电子在异质结界面的迁移率,在AlGaN和GaN [3] HEMTs结构之间插入了10-15 a的AlN势垒。从实验结果来看,基于相同优化的Ti/Al/Mo/Au欧姆金属堆,具有AlN间势垒的未掺杂AlGaN/GaN异质结构更难以获得低接触电阻。在本报告中,为了降低接触电阻,采用相同的材料结构(undped Al.27Ga)。采用73N - 230A/AlN - 15A/GaN),将Ta/Ti/Al/Mo/Au共镀成5个金属层,其中Ti/Al/Mo/Au固定在15 nm/90 nm/40 nm/50 nm, Ta的厚度分别为30、50和75 a。并与在相同材料结构上使用Ta/Ti/Al/Ti/Au金属层的材料进行了电性能比较。如图1所示,在固定Ti/Al/Mo/Au覆盖层的情况下,当厚度为75 a的Ta在700次循环中退火1分钟,然后在800次循环中退火20秒时,转移电阻低至0.105欧姆-毫米。随着Ta层厚度从75 a减小到30 a,转移电阻增加。由于与底层为Ti (4.33 eV)的欧姆金属堆相比,Ta具有更低的功函数(4.25 eV),有利于形成低接触电阻。然而,在内部金属达到薄膜金属特性已经很好建立的厚度之前,势垒高度可能会出现波动[4],这可能与接触电阻对内部薄金属膜厚度的依赖有关。在图1中,金属下面的薄片电阻也通过“端电阻”方法测量,使用75 A Ta的最小值为16.24欧姆/平方。图2和图3分别显示了Ti/Al/Mo/Au和Ti/Al/Ti/Au金属叠层(底部插入Ta)在700℃退火1 min和800℃退火20秒后,总电阻随线性拟合良好的tlm金属间距(0.9997-0.9999)和欧姆触点(9.5 ptm间距)的I-V特性的变化情况。我们可以看到,在相同的退火条件下,使用Ti/Al/Ti/Au作为覆盖层的接触电阻要高得多。可要求800℃以上的较高退火温度以降低电阻。用原子力显微镜测量退火后的表面均方根粗糙度,如图4所示。与Ta/Ti/Al/Mo/Au接触相比,Ta/Ti/Al/Ti/Au接触的表面粗糙度值最高。如图5所示,退火后的Ta 75A/Ti/Al/Mo/Au触点也具有良好的边缘锐度。金属的蠕变小于65 nm。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrical Performance of Ta-Based Ohmic Contacts on Undoped AlGaN/AlN/GaN Heterostructures
Undoped AlGaN/AIN/GaN Heterostructures Yunju Sun and L. F. Eastman 426 Phillips Hall, Cornell University, Ithaca NY 14853 E-mail: _ du Phone: 607-255-1431/607-342-0651 Fax: 607-255-4742 In order to improve the performance of the HFETs, the electrical characteristics of ohmic contacts formed on top of the heterostructures are extremely important in order to achieve a high transconductance and a high saturation current. Previously, thermally stable low resistance with SiCl4 plasma treatment was achieved using Ti/Al/Mo/Au multilayer ohmic contacts on n-GaN [1]. Its thickness and annealing condition were later optimized based on the electrical performance and edge acuity on Undoped AlGaN/GaN HEMTs structure without any plasma surface treatment [2]. The optimized thickness and annealing condition were Ti/Al/Mo/Au (15 nm/90 nm/40 nm/50 nm) and 800 for less than 30 sec respectively. In order to enhance the sheet charge confinement and improve electron mobility at heterojunction interface, a 10-15 A AlN interbarrier was inserted between AlGaN and GaN [3] HEMTs structure. From the experimental results, it was more difficult to get low contact resistance on Undoped AlGaN/GaN heterostructure with AlN interbarrier based on the same optimized Ti/Al/Mo/Au ohmic metal stack. In this report, in order to reduce the contact resistance, same material structure ( Undoped Al.27Ga.73N 230A/AlN 15A/GaN) was used, and Ta/Ti/Al/Mo/Au as a total of five metal layers with Ti/Al/Mo/Au fixed at 15 nm/90 nm/40 nm/50 nm and with Ta at a thickness of 30, 50, and 75 A respectively were evaporated on it. The electrical performance was also compared with the one using Ta/Ti/Al/Ti/Au metal layers on the same material structure. As shown in Fig. 1, with fixed Ti/Al/Mo/Au overlayers, a transfer resistance as low as 0.105 ohm-mm was obtained with Ta at a thickness of 75 A annealed at a cycle of 700 for 1 min followed by 800 for 20 sec. The transfer resistance increased as the Ta layer thickness decreased from 75 A to 30 A. Since comparing with the ohmic metal stack using Ti (4.33 eV) as a bottom layer, Ta has a lower work function (4.25 eV), it can be beneficial for the formation of low contact resistance. However, there could be a fluctuation of barrier height before the inner metal reaches a thickness that the metallic character of the film has been well established [4], which can be related to the dependence of contact resistance on the thickness of inner thin metal film. In Fig. 1, sheet resistance underneath the metal was also measured by "end-resistance" method, and the lowest value is 16.24 ohm/square for the one using 75 A Ta. Fig. 2 and Fig. 3 show the total resistance as a function ofTLM metal spacing with good linear fit (0.9997-0.9999) and I-V characteristics of ohmic contacts (9.5 ptm spacing) after annealing at 700 for 1 min followed by 800 for 20 sec respectively for Ti/Al/Mo/Au and Ti/Al/Ti/Au metal stack with an insertion of Ta as a bottom layer. As we can see, under same annealing condition, the contact resistance is a lot higher using Ti/Al/Ti/Au as overlayers. Higher annealing temperature above 800 can be required to reduce the resistance. The rootmean-square surface roughness after annealing was measured by AFM, as shown in Fig. 4. Ta/Ti/Al/Ti/Au contact has the highest value of surface roughness comparing with those of Ta/Ti/Al/Mo/Au contacts. As shown in Fig.5, the annealed Ta 75A/Ti/Al/Mo/Au contacts also had good edge acuity. The creeping of metal is less than 65 nm.
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