局限于面心立方晶体的多用途双嵌段共聚物教改研究

Yang Yang, Bosen Chai, Miao Miao
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引用次数: 0

摘要

随着教育改革的深入,从分子水平解释机理,将科学研究前沿的机械科学知识融入课堂教学。本文采用分子动力学模拟方法研究了聚合物链在聚合物表面附着形成聚合物刷的过程。根据不同的链结构和反离子来区分表面吸附密度。考虑两种不同的模式:(a)在固定链长的情况下,不同的a块长度;(b)固定a段长度的不同链长。表面吸附势能对二嵌段共聚物链的形状和电刷的形成起着重要的作用。本文研究的吸附密度可为实验人员设计符合要求性能的聚合物刷提供依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Research on Educational Reform of Versatile Diblock Copolymers Confined on the Face Centered Cubic Crystal
With the deepening of educational reform, the mechanism is explained from the molecular level, and the knowledge of mechanical science at the forefront of scientific research is integrated into classroom teaching. In this paper, Molecular Dynamic simulations was used to study the process of polymer brushes formed by the attached of polymer chains on polymer surface. The surface adsorption densities were distinguished according to different chain structures and counter ions. Two different modes are considered: (a) various the A-block lengths at fixed the chain length; (b) various the chain lengths at fixed the A-block length. The surface adsorption potential energy plays an important role in the shape of the diblock copolymer chain and the formation of the brush. The adsorption density studied in this paper can provide a basis for experimenters to design polymer brushes with required properties.
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