菠萝蛋白酶基聚乙烯醇纤维的制备与表征

J. Sundar, R. Subramanian, N. Venkateshwaran, R. Jayasree, A. Saravanan
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摘要

在过去的十年中,聚乙烯醇因其高机械性能、化学和热稳定性、无毒性质、成膜能力和低制造成本等显著特性而得到了广泛的应用。聚乙烯醇具有广泛的工业用途,如纺织、造纸、食品包装等行业,并可作为可生物降解产品,如背辊、粘合剂、涂料、表面活性剂等。但迄今为止,聚乙烯醇具有断裂伸长率低的缺点。此外,由于在熔化过程中具有高粘性,因此难以成型。为了提高菠萝蛋白酶基聚乙烯醇纤维的柔韧性、热性能和力学性能,本课题主要研究了菠萝蛋白酶基聚乙烯醇纤维的制备和表征。这样制备的纤维可用于3D打印应用,作为复杂形状建模的支撑结构,生产用于炎症伤口的绷带或湿巾,食品包装容器等。本研究以菠萝蛋白酶为添加剂,在不同的化学计量比下对聚乙烯醇进行了分析。采用甘油作为增塑剂,提高其柔韧性和强度。试验结果为:最大抗拉强度为7.66 Mpa,三点弯曲试验的最大制动载荷和应力分别为35 N和2.593 Mpa,通过TG/DTA分析得出添加菠萝蛋白酶后的温度变化范围,了解其延展性、抗拉强度、强度增强、热稳定性等,并通过观察和记录SEM图像研究其内部结构。因此,对定制的原料进行了测试和分析,以了解其性能的变化,从而扩大其应用范围。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation and characterization of bromelain based poly-vinyl alcohol fiber
In the last decade, the applications of polyvinyl alcohol have expanded for its notable characteristics like high mechanical properties, chemical and thermal stability, non-toxic nature, film forming capabilities, and low manufacturing cost [1]. Poly-vinyl alcohol has a wide range of industrial application like textile, paper industry, food packaging industry, and as a biodegradable product like backing rolls, adhesives, coatings, surfactant etc. But hitherto, Poly-Vinyl alcohol has certain disadvantages like lower breaking elongation. Also, it is difficult to mold as it is highly viscous nature during the melting process [2]. The present research work is focused on preparation and studying the characterization of Bromelain based Poly-vinyl Alcohol fiber to improve its flexibility, thermal and mechanical characteristics. The fiber thus prepared may be employed in 3D printing application as support structures for modeling intricate shapes, production of bandages or wipes for inflammation wounds, Food packaging containers etc. For the present study, polyvinyl alcohol is tailored with Bromelain (Pineapple enzyme) which is used as an additive in this process and was analyzed in different stoichiometric ratios. Glycerin was employed as plasticizer to improve its flexibility and strength. The results that was inferred from the tests are namely: maximum tensile strength of 7.66 Mpa, maximum brake load and stress from three-point bending test was found to be 35 N and 2.593 Mpa, the temperature range shifts on addition of Bromelain was derived from TG/DTA analysis to understand its ductility, tensile strength, strength enhancement, thermal stability etc., and observation and recording of SEM images for studying its internal structure. Therefore, the tailored feedstock was tested and analyzed to understand the variation in its properties thus broadening its applications.
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