Dupeng Liu, Nawa Raj Baral, Ling Liang, C. Scown, N. Sun
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We further compared the revenue generated from the torrefied biomass and bioethanol derived from the same quantity of almond shells. We considered three different torrefaction facility scales to evaluate trade-offs between economies of scale at the facility and trucking costs to deliver almond shells. A facility that takes in 200 000 MT yr–1 of almond shells results in lower per-unit-output basis capital and operating cost relative to other smaller-scale torrefaction facilities, including 10 000 MT yr–1 and 50 000 MT yr–1, considered for analysis in this study. The large-sale facility results in a minimum selling price (MSP) of the torrefied biomass of $311.4 MT–1. An analogous TEA on converting almond residues into bioethanol is also investigated. The MSP of almond shell derived ethanol ($1.71 kg−1) is higher than that of corn ($0.48 kg−1) or cellulosic biomass ($0.88 kg−1) derived ethanol. 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引用次数: 2
摘要
2016年,仅美国加利福尼亚州就生产了近35亿公斤杏仁,约占世界杏仁产量的84%。这产生了大约258万公吨的杏仁残留物。目前,杏仁壳要么被焚烧发电,要么被填埋。杏仁壳和壳的增值为替代石油衍生产品和从垃圾填埋场转移有机材料提供了机会。在这里,我们展示了一个详细的技术经济分析(TEA)的杏仁壳烘烤过程能够利用在加利福尼亚每年生产的520,000吨杏仁壳。我们的工艺还包括预处理碳化生物质,利用它作为塑料的增强剂。我们进一步比较了碳化生物质和从相同数量的杏仁壳中提取的生物乙醇产生的收入。我们考虑了三种不同的焙烧设施规模,以评估设施规模经济与运送杏仁壳的运输成本之间的权衡。与其他规模较小的炼油设施(包括1万吨/年和5万吨/年)相比,年产20万吨杏仁壳的设施的单位产出基础资本和运营成本较低,本研究考虑了这一点。大型销售设施导致碳化生物质的最低销售价格(MSP)为311.4 MT-1美元。还研究了一种类似的将杏仁渣转化为生物乙醇的TEA。杏仁壳衍生乙醇的MSP ($1.71 kg - 1)高于玉米($0.48 kg - 1)或纤维素生物质($0.88 kg - 1)衍生乙醇。与生物乙醇路线相比,碳化杏仁壳如果用作塑料的增强剂,其收益是生物乙醇路线的三倍。
Torrefaction of almond shell as a renewable reinforcing agent for plastics: techno-economic analyses and comparison to bioethanol process
In 2016, the US state of California alone produced nearly 3.5 billion kilograms of almonds, accounting for approximately 84% of the world’s almond production. This generated about 2.58 million metric tons (MTs) of almond residues. Almond shells are currently either burned to generate power or disposed of in landfill. Valorizing almond shells and hulls provides an opportunity to replace petroleum-derived products and divert organic material from landfill. Here we demonstrate a detailed techno-economic analysis (TEA) of an almond shell torrefaction process capable of utilizing the 520 000 MTs of almond shells produced annually in California. Our process also includes preprocessing the torrefied biomass to exploit it as a reinforcing agent for plastics. We further compared the revenue generated from the torrefied biomass and bioethanol derived from the same quantity of almond shells. We considered three different torrefaction facility scales to evaluate trade-offs between economies of scale at the facility and trucking costs to deliver almond shells. A facility that takes in 200 000 MT yr–1 of almond shells results in lower per-unit-output basis capital and operating cost relative to other smaller-scale torrefaction facilities, including 10 000 MT yr–1 and 50 000 MT yr–1, considered for analysis in this study. The large-sale facility results in a minimum selling price (MSP) of the torrefied biomass of $311.4 MT–1. An analogous TEA on converting almond residues into bioethanol is also investigated. The MSP of almond shell derived ethanol ($1.71 kg−1) is higher than that of corn ($0.48 kg−1) or cellulosic biomass ($0.88 kg−1) derived ethanol. Compared with the bioethanol route, the torrefied almond shells result in three times more revenue if utilized as a reinforcing agent for plastics.