{"title":"N/ sub2 /气体的电化学还原及其在能源系统中的应用","authors":"Y. Ito, T. Goto","doi":"10.1109/IECEC.1997.660266","DOIUrl":null,"url":null,"abstract":"We have found that N/sub 2/ gas is subject to a cathodic reduction to form N/sup 3-/ ion in a molten chloride system. This new finding is encouraging us to consider the possibility of several energy conversion related electrochemical processes, i.e., thermally regenerative fuel cell with Li-N/sub 2/ couple, ammonia synthesis from N/sub 2/ and H/sub 2/O, and electrochemical implantation of N atom into metal surface to form energy material. In order to provide available data for considering these possibilities, cathodic reduction of N/sub 2/ gas, anodic oxidation of N/sup 3-/ ion and electrochemical surface nitriding reaction in molten chloride were investigated in detail.","PeriodicalId":183668,"journal":{"name":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","volume":"32 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1997-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"The electrochemical reduction of N/sub 2/ gas and its application to energy systems\",\"authors\":\"Y. Ito, T. Goto\",\"doi\":\"10.1109/IECEC.1997.660266\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"We have found that N/sub 2/ gas is subject to a cathodic reduction to form N/sup 3-/ ion in a molten chloride system. This new finding is encouraging us to consider the possibility of several energy conversion related electrochemical processes, i.e., thermally regenerative fuel cell with Li-N/sub 2/ couple, ammonia synthesis from N/sub 2/ and H/sub 2/O, and electrochemical implantation of N atom into metal surface to form energy material. In order to provide available data for considering these possibilities, cathodic reduction of N/sub 2/ gas, anodic oxidation of N/sup 3-/ ion and electrochemical surface nitriding reaction in molten chloride were investigated in detail.\",\"PeriodicalId\":183668,\"journal\":{\"name\":\"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)\",\"volume\":\"32 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1997-12-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/IECEC.1997.660266\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IECEC-97 Proceedings of the Thirty-Second Intersociety Energy Conversion Engineering Conference (Cat. No.97CH6203)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/IECEC.1997.660266","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The electrochemical reduction of N/sub 2/ gas and its application to energy systems
We have found that N/sub 2/ gas is subject to a cathodic reduction to form N/sup 3-/ ion in a molten chloride system. This new finding is encouraging us to consider the possibility of several energy conversion related electrochemical processes, i.e., thermally regenerative fuel cell with Li-N/sub 2/ couple, ammonia synthesis from N/sub 2/ and H/sub 2/O, and electrochemical implantation of N atom into metal surface to form energy material. In order to provide available data for considering these possibilities, cathodic reduction of N/sub 2/ gas, anodic oxidation of N/sup 3-/ ion and electrochemical surface nitriding reaction in molten chloride were investigated in detail.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
