基于角菱矿的新型热电化合物。铈填充镍取代角长石Ce/sub - y/Fe/sub - 4-x/Ni/sub -x/ Sb/sub - 12/型XANES及中子衍射研究

Eighteenth International Conference on Thermoelectrics. Proceedings, ICT'99 (Cat. No.99TH8407) Pub Date : 1999-08-29 DOI:10.1109/ICT.1999.843323

L. Chapon, D. Ravot, J. Tedenac, F. Bouree-Vignerons

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摘要

填充和部分填充的方角石的低导热系数是由填充原子的特殊性质决定的。为了更好地理解这种行为，我们对Ce/sub y/Fe/sub 4-x/Ni/sub x/Sb/sub 12/类化合物进行了XANES和中子衍射实验。

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Skutterudite based new thermoelectric compounds. Cerium filled Ni substituted skutterudites Ce/sub y/Fe/sub 4-x/Ni/sub x/Sb/sub 12/ type XANES and neutron diffraction studies

Low thermal conductivity of filled and partially filled skutterudites is due to specific properties of filling atom. In order to achieve a better fundamental understanding of this behavior, we have performed XANES and neutron diffraction experiments for the Ce/sub y/Fe/sub 4-x/Ni/sub x/Sb/sub 12/ class compounds.

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Eighteenth International Conference on Thermoelectrics. Proceedings, ICT'99 (Cat. No.99TH8407)

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