V. Chornii, V. Boyko, S. Nedilko, V. Scherbatskyi, K. Terebilenko, P. Teselko, O. Gomenyuk, Vadym Sheludko
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引用次数: 0
摘要
本文报道了以纤维素为基体,以掺镨钼酸铋钾和纳米颗粒为填料的复合材料的制备过程、形貌和发光性能。光学显微镜和扫描电镜显示样品在100以上的尺度上均匀性$\mu\mathrm{m}$。氧化颗粒的粒径分布范围为$\sim 100$ nm ~ 3$\mu \mathrm{m}$。化学元素分析表明,氧化物和聚合物组分在研究区内分布均匀。当复合激发为448 nm时,样品显示出$\text{Pr}^{3+}$离子的强光致发光,而在较短的波长- 405 nm下,样品显示纤维素相关的发光。温度对复合材料发光特性影响的研究表明,温度在18 - $75\ ^{\circ}\mathrm{C}$范围内,$\text{Pr}^{3+}\text{-}$相关发光强度在约40时减小 %, while cellulose-related photoluminescence decreases on about 20%. The composites under study are prospective materials for elaboration of luminescent light emitting diodes covers.
Morphology and Luminescence Properties of Cellulose+KBi0.99Pr0.01 (MoO4)2 Composites
The procedure of the samples preparation, morphology and luminescence properties of composites those consist of cellulose matrix and praseodymium-doped potassium bismuth molybdate micro- and nanoparticles as a filler are reported. The optical and scanning electron microscopy has shown the homogeneity of the samples in the scale above 100 $\mu\mathrm{m}$. The size distribution of oxide particles is found to be in a range from $\sim 100$ nm up to 3 $\mu \mathrm{m}$. Chemical element analysis indicates uniform distribution of oxide and polymer components over the studied area. The samples reveal intensive photoluminescence of $\text{Pr}^{3+}$ ions if composite excitation is at 448 nm and cellulose-related luminescence under excitation at shorter wavelength −405 nm. The study of influence of temperature on luminescence characteristics of composites in the temperature range 18 - $75\ ^{\circ}\mathrm{C}$ shows that intensity of $\text{Pr}^{3+}\text{-}$ related luminescence decreases on about 40 %, while cellulose-related photoluminescence decreases on about 20%. The composites under study are prospective materials for elaboration of luminescent light emitting diodes covers.