高导电性无铅导电胶粘剂的研制

S.K. Kang, R. Rai, S. Purushothaman
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引用次数: 69

摘要

导电胶粘剂技术是目前正在积极研究的替代方案之一,有望取代用于微电子应用的焊料互连技术。一种各向同性导电胶粘剂由分散在聚合物树脂基体中的金属填充颗粒组成。填充银的环氧树脂通常用于热传导在模具附着的应用。银颗粒可以提供电和/或热传导,而环氧树脂提供组件与基材的粘合剂粘合。当它被认为是焊料互连的替代品时,这种材料有几个限制,例如低导电性,低连接强度,热循环时接触电阻增加,缺乏可再加工性和银迁移。为了克服这些限制,提出了一种基于替代无铅导电填料粉和定制聚合物树脂的新配方。导电填料颗粒表面涂有低熔点、无毒的金属,这些金属可以熔合以实现相邻颗粒之间以及与衬底之间的冶金结合。与现有的银填充环氧树脂材料相比,这种新型导电粘接材料具有更好的电气和机械性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Development of high conductivity lead (Pb)-free conducting adhesives
Electrically conducting adhesive technology is one of the alternatives being actively investigated for the possibility of replacing the solder interconnection technology used for microelectronics applications. An isotropically conducting adhesive consists of metallic filler particles dispersed in the matrix of a polymer resin. Silver-filled epoxy resin is commonly used for thermal conduction in die attach applications. Silver particles can provide electrical and/or thermal conduction, while epoxy provides adhesive bonding of the components to a substrate. This material has several limitations when it is-considered as a replacement for solder interconnections, such as low electrical conductivity, low joint strength, increase in contact resistance upon thermal cycling, lack of reworkability, and silver migration. In order to overcome these limitations, a new formulation is proposed based on alternative Pb-free conducting filler powder and tailored polymer resins. The conducting filler particles are coated with low melting point, non-toxic metals which can be fused to achieve metallurgical bonding between adjacent particles as well as to a substrate. This new conductive adhesive material has shown improved electrical and mechanical properties over the existing silver-filled epoxy materials.
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