钛-铜金属基复合材料的本征改性和界面行为

Y. Fouad, B. Rabeeh
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摘要

在750 ~ 950℃的温度范围内,在真空条件下,单轴压力为3mpa,分别进行了0.5、1、2 h的单轴热压试验。采用热压法制备Ti/Cu-Zn/Ti箔层,形成对称排列的层状复合材料结构。工业纯钛与铜锌(黄铜)之间的扩散键合。利用光学显微镜和扫描电镜对扩散区的微观结构进行了分析。用能量色散x射线能谱分析了扩散物质在界面上的相互扩散。用x射线衍射技术鉴定了在界面处形成的反应产物。结果表明,扩散区主要存在偏析Ti侧的低熔点抑制剂Zn和靠近钛侧的β-Ti固溶体(溶质为Zn、Cu和Ni)。在相间反应区发现Cu、Zn和Ti的存在。在800℃时,界面结合强度最高(~200 MPa),随连接温度的升高而降低。过渡接头强度的变化与扩散区的显微组织特征有关。介绍了不同微观成分在纯钛铜锌层间键合中的应用。复合过程中,间相控制起主导作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Intrinsic modification and interfacial behavior in a titanium-copper metal matrix composite
The application of hot uniaxial pressing has been carried out in the temperature range of 750-950 °C for 0.5, 1 and 2 h at uniaxial pressure of 3 MPa in vacuum. Ti/Cu-Zn/Ti foil-foil layup are hot pressed for a lamellar composite structure symmetrically arranged. Inter diffusion bonding between commercially pure titanium and Copper-Zinc (brass) is applied. The microstructure of the diffusion zone has been analyzed by optical and scanning electron microscopy (SEM). The inter diffusion of the diffusing species across the interface has been evaluated by energy dispersive X-ray spectroscopy EDX. The reaction products formed at the interface have been identified by X-ray diffraction technique. It has been observed that the diffusion zone is dominated by the presence of the low melting depressant (LMD) Zn that segregate into Ti side and the solid solution of β-Ti (solutes are Zn, Cu and Ni) close to the titanium. The presence of Cu and Zn and Ti has been found in the interphase reaction zone. It has been observed that the interfacial bond strength (~200 MPa) is highest for the couple processed at 800 °C and this value decreases with rise in joining temperature. The variation of strength of the transition joints is co-related with the microstructural characteristics of the diffusion zone. The application of brass (Cu-Zn) interlayer bonding of pure titanium introduced with different micro constituents. The control of interphase is dominant for composite processing.
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