解决甲醇净化“呼吸”气体的环境问题

V. Bochkarev, O. Kukurina, A. Vdovin
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引用次数: 0

摘要

确定了CJSC“甲醇”(托木斯克,俄罗斯)上的罐和铁路罐中甲醇“呼吸”气体清洗效率下降的真正原因。铂催化剂的老化是由于陶瓷块的烧结和部分破坏造成的,这些破坏是由于极限使用温度过高、活性中心被焦炭堵塞、催化装置的非最佳工作等原因造成的。提出了块体铂催化剂再生的经济途径。研究了甲醇在铂和金属络合催化剂上的深度氧化动力学。此外,还定义了“呼吸”气体净化装置的最佳操作。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Solving environmental problems of “breathing” gases purification from methanol
The true reasons of decrease in efficiency of "breathing" gases cleaning of tanks and railway tanks from methanol on CJSC "Methanol" (Tomsk, Russia) are determined. Platinum catalyst aging is caused by sintering and partial destruction of ceramic blocks owing to excess of ultimate service temperature, blocking of the active centers by coke, nonoptimum working of the catalytic installation. The economic way of block platinum catalysts regeneration is developed. Also the kinetics of the methanol deep oxidation on platinum and metal-complex catalysts is investigated. Moreover optimal operation of installation for "breathing" gases purification is defined.
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