(Bi/sub - 2/Te/sub - 3/)(Sb/sub - 2/Te/sub - 3/)(Sb/sub - 2/Se/sub - 3/)区熔材料生产过程中化学反应平衡的变化

Proceedings ICT2001. 20 International Conference on Thermoelectrics (Cat. No.01TH8589) Pub Date : 2001-06-08 DOI:10.1109/ICT.2001.979835

O. B. Sokolov, S. Skipidarov, N. I. Duvankov

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摘要

采用热力学计算和差热分析的方法，研究了在安瓿中合成(Bi/sub 2/Te/sub 3/)/sub x/(Sb/sub 2/Te/sub 3/)/sub y/(Sb/sub 2/Se/sub 3/)/sub z/ (x+y+z=100%)的化学平衡变化对垂直区熔法生长晶体特性的影响。

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The variation of the equilibrium of chemical reactions in the process of (Bi/sub 2/Te/sub 3/)(Sb/sub 2/Te/sub 3/)(Sb/sub 2/Se/sub 3/) zone-melted material production

Methods of thermodynamic computation and differential thermal analysis were used for research into the effect of the variation of the chemical equilibrium in the synthesis of (Bi/sub 2/Te/sub 3/)/sub x/(Sb/sub 2/Te/sub 3/)/sub y/(Sb/sub 2/Se/sub 3/)/sub z/ (x+y+z=100%) in an ampoule on the characteristics of crystals grown by the vertical zone-melting technique.

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Proceedings ICT2001. 20 International Conference on Thermoelectrics (Cat. No.01TH8589)

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