用于不同传感应用的纯氧化锌(半导体)和ZnO:Ga纳米结构的合成

M. Hassan, Asma Muhammad, W. Mahdi, Nizar Mahan, Amani Kamil, I. Alwan, Afrah Shanshal
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引用次数: 0

摘要

本研究采用简单的化学工艺和廉价的材料制备ZnO和ZnO:Ga,即水热法,在制备的电池中加入0.05M的硝酸锌和0.05M的六亚甲基四胺(C6H12N4)。该电池在实验室烤箱中恒温至150℃,持续8小时。4%氮化镓Ga (NO3)3用于制备浸渍Ga的氧化锌。在磁力搅拌器的连续搅拌作用下,将xH2O加入到之前制备的溶液中。在水热法的发展过程中,研究了几种影响,通过快速热氧化250 nm的金属锌在氧化锌层上沉淀作为预先制备的种子层,以达到最佳的条件,从而获得最佳的应用效果。本文还对制备的氧化锌纳米结构的光学性质和合成性质进行了研究和分析。这些制备的膜已在最佳条件下用作多用途传感器:气体传感器,其中ZnO:Ga沉积在石英涂层的氧化锑锡的基础上,作为非常危险的氢气的气体传感器。研究了不同气体浓度对ZnO:Ga电阻随时间的影响。我们还研究和制造了高效率的太阳能电池传感器,使用的是曼苏尔国有公司配备的伊拉克材料和当地市场上可以买到的简单传统设备。本文设计了一种机械传感器来监测含盐量,改善水质。受体(其中电池放置在两端之间:一端代表压电段,另一端代表ZnO:Ga沉淀在涂有氧化锑锡的石英的134个碱基上)。本研究使用的工作频率范围为1500- 20000khz。本研究的测试包括记录所有制备样品的第一阶谐振频率,并计算阻尼系数作为时间的函数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis of pure Zinc Oxid (Semiconductor) and ZnO:Ga Nanostructure for Different Sensing Applications
The research involved the preparation of ZnO and ZnO:Ga by a simple chemical process and inexpensive materials, namly a hydrothermal method by adding 0.05M of zinc nitrate and 0.05M of hexamethylenetetramine (C6H12N4) to the cell manufactured for this purpose. The cell is in a laboratory oven for eight hours at a constant temperature up to 150 oC. For preparing of zinc oxide impregnated with Ga, 4% gallium nitride Ga (NO3)3.xH2O is added to the previous prepared solution under continuous stirring effect using a magnetic mixer. Several effects have been studied in the development of this hydrothermal method, which are precipitated on the zinc oxide layer as a pre-prepared seed layer by fast thermal oxidation of zinc metal 250 nm to achieve optimal conditions leading to the best results for applications. The work also included a study and analysis of the optical and synthetic properties of the prepared zinc oxide nanostructure. These prepared membranes have been used in the best conditions as a multi-application sensors: gas sensors where the ZnO:Ga deposited on the basis of quartz coated with antimony tin oxide as a gas sensor for very dangerous hydrogen gas. The effect of different concentration of gas on resistance of ZnO:Ga over time has been studied. We also studied and manufactured sensors that work as solar cells with high efficiency using Iraqi materials equipped with Al-Mansour State Company and simple conventional devices available in the local market. In this paper, a mechanical sensor is designed to monitor the salt content and improve the water quality. Receptors (where the cell is placed between two ends: the first end represents a piezo segment and the second end represents the ZnO:Ga precipitated on the 134 bases of quartz coated with antimony tin oxide). The range of operating frequencies used in this research ranges from 1500-20000 KHz. Tests in this research included recording the resonant frequency at the first rank of all prepared samples and calculating the damping factor as a function of time.
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