壳聚糖复合材料对水中有毒铅(II)离子的吸附研究

Asha H. Gedam, Prashil K. Narnaware, V. Kinhikar
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引用次数: 4

摘要

环境污染是由重金属、有机污染物、放射性物质、农药、染料、色素、脂肪/油杂质和矿物质引起的周围毒性的不利改变,这些因素对生态和健康有重要影响。不分青红皂白的工业和人类活动使水资源不适合消费。合成污染物在水中的渗透是对水生动植物造成有害影响的原因。水的环境污染是开发基于生物聚合物使用的高效水处理技术的主要挑战。因此,壳聚糖(去乙酰化甲壳素:β-(1→4)d -氨基葡萄糖)是一种廉价、可生物降解、生物相容性好的生物吸附剂。通过掺入少量有机/无机基团修饰壳聚糖的柔性骨架,制备了吸附多种污染物的生物复合材料。本章讨论了石墨掺杂壳聚糖复合物(GDCC)作为吸附剂对水中有毒铅(II)离子的批量吸附。在最佳pH为6、投加量为1 g/L、120 min的条件下,最大Pb (II)离子吸附量为6.711 mg/g(来自Langmuir)。在废水净化过程中强调了生物吸附机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Blended Composites of Chitosan: Adsorption Profile for Mitigation of Toxic Pb (II) Ions from Water
An environmental pollution is the unfavorable alteration of surrounding toxicity due to heavy metals, organic pollutants, radioactive materials, pesticides, dyes, pigments, fatty/ oil impurities and minerals that are responsible for crucial ecological and health con- cerns. The indiscriminate industrial and anthropological activities render water resources unsuitable for consumptions. Percolations of synthetic pollutants in water are respon- sible for detrimental effects on aquatic flora and fauna. Environmental contamination of water poses the major challenge to develop efficient water treatment techniques based on usage of biopolymers. Hence, chitosan (de-acetylated chitin: β-(1 → 4) D-glucosamine ) bio-sorbent is preferred which is cheap, biodegradable, and biocompatible for the mitigation of few heavy metals from water. Chitosan’s flexible skeleton was modified by doping few organic/inorganic moieties to yield biocomposites for adsorption of varied pollutants. In this chapter, the batch adsorption of toxic Pb (II) ions from water using graphite doped chitosan composite (GDCC) as an adsorbent is discussed. Maximum Pb (II) ions adsorp - tion capacity was 6.711 mg/g (from Langmuir) at optimum pH 6 with dosage of 1 g/L in 120 min. Biosorption mechanism is emphasized in context with wastewater cleanup procedures.
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