活性炭吸附镉的动力学分析

Faggo Abdullahi Adamu, Khalizan Sabullah, Umar Abubakar Muhammad, N. A. Yasid, M. Shukor
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引用次数: 0

摘要

虽然近几十年来Cd的生产、消费和环境释放都在飞速增长,但目前还没有切实可行的方法来回收Cd化合物。这表明,镉化合物可能对人体健康非常危险。因此,镉污染环境的修复刻不容缓。几种可行的技术包括生物吸附,它有几个积极的方面,包括低操作费用,在低浓度下非常有效地解毒和少量的处理材料。采用非线性回归方法对活性炭对镉的生物吸附进行了重构,并通过一系列误差函数评估确定了最优模型。统计分析表明,最佳的吸附动力学模型为准一级。所有误差函数分析都支持伪一阶模型。拟一级动力学常数qe (mg/g)为5.808(95%置信区间为5.043 ~ 6.573),k1(每分钟)为0.009(95%置信区间为0.0064 ~ 0.0117)。非线性建模可以确定不确定性范围的95%置信区间,可用于模型比较和判别分析。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Kinetic Analysis of the Adsorption of Cadmium onto Activated Carbon from Tridax procumbens
While Cd production, consumption, and environmental release have all skyrocketed in recent decades, there is currently no practical way to recycle Cd compounds. This suggests that Cd compounds may be very dangerous to human health. Due to this cadmium remediation from polluted environment is urgently needed. Several viable technologies include biosorption, which has several positive aspects which include low operating expenses, very efficient detoxification of toxicants at low concentrations and low amount of disposal materials. The biosorption of the biosorption of cadmium onto the activated carbon from Tridax procumbens is remodeled using nonlinear regression and the optimal mode was determined by a series of error function assessments. Statistical analysis showed that the best kinetic model for adsorption was pseudo-1st order. All error function analyses supported the pseudo-1st order model. The pseudo-1st order kinetic constants obtained were qe (mg/g) of 5.808 (95% confidence interval from 5.043 to 6.573) and k1 (per min) of 0.009 (95% confidence interval from 0.0064 to 0.0117). Nonlinear modeling enables the determination of a 95 percent confidence interval for the uncertainty range, which can be used in model comparison and discriminant analysis.
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